Citation: LI Jie, TIAN Shu-Fang, ZHOU Hui, MA Peng-Tao. A New Organic-inorganic Hybrid Arsenatotungstate [{Cu(phen)(en)}{Cu(phen)}{Cu₃(phen)₃(α-AsW₉O₃₃)}](OH)·3H₂O[J]. Chinese Journal of Structural Chemistry, ;2015, 34(8): 1247-1252. doi: 10.14102/j.cnki.0254-5861.2011-0652 shu

A New Organic-inorganic Hybrid Arsenatotungstate [{Cu(phen)(en)}{Cu(phen)}{Cu₃(phen)₃(α-AsW₉O₃₃)}](OH)·3H₂O

1.
Key Laboratory of Polyoxometalate Chemistry of Henan Province, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, Henan 475004, China

Corresponding author: MA Peng-Tao,
Received Date: 29 January 2015
Available Online: 29 April 2015
Fund Project: This work was supported by the Foundation of Education Department of Henan Province (14A150028) (14A150028)

A new organic-inorganic hybrid copper-substituted arsenatotungstate complex formulated as [{Cu(phen)(en)}{Cu(phen)}{Cu₃(phen)₃(α-AsW₉O₃₃)}](OH)·3H₂O (1, en=ethylene-diamine, 1,10-phen=1,10-phenanthroline) has been synthesized by controlling the reaction process and characterized by infrared (IR) spectroscopy, elemental analysis, and thermogravimetric (TG) analysis. Crystal data for 1: C₆₂H₅₆AsCu₅N₁₂O₃₇W₉, M_r=3608.46, monoclinic, space group P2₁/c, a=13.245(4), b=25.692(9), c=24.670(8)Å, β=99.251(6)°, V=8286(5)Å³, Z=4, GOOF=1.103, R=0.0560, wR=0.1285. In 1, the vacant sites of the trivacant Keggin anion [α-AsW₉O₃₃]^9- are occupied by three same copper coordination cations [Cu(phen)]²⁺. Meanwhile, the lacunary anion [α-AsW₉O₃₃]^9- is capped by two kinds of copper coordination cations [Cu(phen)]²⁺ and [Cu(phen)(en)]²⁺, resulting in an unprecedented polycation structure with C_s symmetry.
- tungstoarsenate,
- hydrothermal,
- crystal structure
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