Citation: YAO Hua-Gang, ZHANG Jun-Jun, CAI Zhang-Wei, ZHANG Chen-Yang, YOU Li-Jun, ZHENG Shuang. A New Zn(II) Coordination Polymer Constructed by 1,4-Benzenedithiolate Dianion: [Zn(SC₆H₄S)(1,3-DPA)]_n[J]. Chinese Journal of Structural Chemistry, ;2015, 34(6): 911-916. doi: 10.14102/j.cnki.0254-5861.2011-0625 shu

A New Zn(II) Coordination Polymer Constructed by 1,4-Benzenedithiolate Dianion: [Zn(SC₆H₄S)(1,3-DPA)]_n

1.
School of Chemistry and Chemical Engineering, Guangdong Pharmaceutical University, Zhongshan 528458, China

Corresponding author: YAO Hua-Gang,
Received Date: 4 January 2015
Available Online: 9 April 2015
Fund Project: Supported by the National Natural Science Foundation of China (No.21301035) (No.21301035)

A new one-dimensional polymer, [Zn(SC₆H₄S)(1,3-DPA)]_n (1, SC₆H₄S=1,4-benzenedithiolate and 1,3-DPA=1,3-diaminepropane), has been synthesized and characterized by elemental analysis, PXRD, IR spectra, and single-crystal X-ray diffraction. The complex crystallizes in triclinic system, space group P1, with a=6.7119(1), b=9.0230(2), c=10.4943(2) Å, α=69.288(1), β=75.848(1), γ=81.513(1)°, V=575.123(19) Å³, D_c=1.615 g/cm³, Z=2, F(000)=288; the final S=1.070, R=0.0234, and wR=0.0551. The compound consists of an infinite zigzag chain formed by [Zn(1,3-DPA)]²⁺ units joined by SC₆H₄S ligands. Each chain interacts with neighboring chains via weak N-H···S hydrogen bonds to form an extended three-dimensional (3D) supramolecular network. The thermal and photoluminescent properties of 1 have also been investigated.
- Zn(Ⅱ)coordination polymer,
- crystal structure,
- 1,4-benzenedithiol,
- zigzag chain
1. [1]
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2. [2]
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3. [3]
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4. [4]
  Chao LIU , Jiang WU , Zhaolei JIN . Synthesis, crystal structures, and antibacterial activities of two zinc(Ⅱ) complexes bearing 5-phenyl-1H-pyrazole group. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1986-1994. doi: 10.11862/CJIC.20240153
5. [5]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
6. [6]
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7. [7]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
8. [8]
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9. [9]
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10. [10]
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11. [11]
  Yan XU , Suzhi LI , Yan LI , Lushun FENG , Wentao SUN , Xinxing LI . Structure variation of cadmium naphthalene-diphosphonates with the changing rigidity of N-donor auxiliary ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 395-406. doi: 10.11862/CJIC.20240226
12. [12]
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13. [13]
  Ruikui YAN , Xiaoli CHEN , Miao CAI , Jing REN , Huali CUI , Hua YANG , Jijiang WANG . Design, synthesis, and fluorescence sensing performance of highly sensitive and multi-response lanthanide metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 834-848. doi: 10.11862/CJIC.20230301
14. [14]
  Meirong HAN , Xiaoyang WEI , Sisi FENG , Yuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu²⁺. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150
15. [15]
  Shuyan ZHAO . Field-induced Co^Ⅱ single-ion magnet with pentagonal bipyramidal configuration. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1583-1591. doi: 10.11862/CJIC.20240231
16. [16]
  Yinling HOU , Jia JI , Hong YU , Xiaoyun BIAN , Xiaofen GUAN , Jing QIU , Shuyi REN , Ming FANG . A rhombic Dy₄-based complex showing remarkable single-molecule magnet behavior. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 605-612. doi: 10.11862/CJIC.20240251
17. [17]
  Zhaodong WANG . In situ synthesis, crystal structure, and magnetic characterization of a trinuclear copper complex based on a multi-substituted imidazo[1,5-a]pyrazine scaffold. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 597-604. doi: 10.11862/CJIC.20240268
18. [18]
  Shuwen SUN , Gaofeng WANG . Design and synthesis of a Zn(Ⅱ)-based coordination polymer as a fluorescent probe for trace monitoring 2, 4, 6-trinitrophenol. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 753-760. doi: 10.11862/CJIC.20240399
19. [19]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
20. [20]
  Huiju Cao , Lei Shi . sp¹-Hybridized linear and cyclic carbon chain. Chinese Chemical Letters, 2025, 36(4): 110466-. doi: 10.1016/j.cclet.2024.110466