Citation: LU Jiu-Fu, GE Hong-Guang, SHI Juan. Synthesis, Crystal Structure and Fluorescence Property of the Ag(Ⅰ) Coordination Polymer Constructed by 21D [Ag(1,3-BIP)(PMA)_0.5]_n^n- Layers and 1D [Ag(1,3-BIP)(H₂O)]_nⁿ⁺ Chains[J]. Chinese Journal of Structural Chemistry, ;2015, 34(8): 1259-1264. doi: 10.14102/j.cnki.0254-5861.2011-0612 shu

Synthesis, Crystal Structure and Fluorescence Property of the Ag(Ⅰ) Coordination Polymer Constructed by 21D [Ag(1,3-BIP)(PMA)_0.5]_n^n- Layers and 1D [Ag(1,3-BIP)(H₂O)]_nⁿ⁺ Chains

1.
Chemical Engineering College, Shaanxi University of Technology, Hanzhong 723001, China

Received Date: 24 December 2014
Available Online: 25 June 2015
Fund Project: Supported by the National Natural Science Foundation of China (No. 21373132) (No. 21373132)the Science Foundation of Shaanxi University of Technology (No. SLGKY-36) (No. SLGKY-36)

A new Ag(Ⅰ) coordination polymer, {[Ag(1,3-BIP)(H₂O)][Ag(1,3-BIP)(PMA)_0.5·4H₂O}_n (PMA=1,2,4,5-benzenetricarboxylic acid, 1,3-BIP=1,3-bis(imidazole)propane), have been synthesized and characterized by single-crystal X-ray diffraction, powder XR1D, FTIR, TGA and elemental analysis techniques. The single-crystal X-ray diffraction reveals that the title complex is formed by 1D polymeric cationic chains of [Ag(1,3-BIP)(H₂O)]_nⁿ⁺ and 2D polymetric anionic layer of [Ag(1,3-BIP)(PMA)_0.5]_n^n-, which are further linked by intermolecular H-bonding to form a 3D supramolecular framework. In addition, the photoluminescence property of the title complex in the solid state at room temperature was also investigated.
- Ag(Ⅰ) coordination polymer,
- helical chains,
- photoluminescence property
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