Citation: GAO Rui, ZHAO Yong, JIANG Dao-Yong, DING Guo-Hua. Synthesis, Structure and Photophysical Property of the Schiff Base on N,N-Ethylene-bis(3,5-dichlorosalicylideneimine) and Its Salen-Co(II) Complex[J]. Chinese Journal of Structural Chemistry, ;2015, 34(5): 741-748. doi: 10.14102/j.cnki.0254-5861.2011-0608 shu

Synthesis, Structure and Photophysical Property of the Schiff Base on N,N-Ethylene-bis(3,5-dichlorosalicylideneimine) and Its Salen-Co(II) Complex

1.
College of Chemical and Bioengineering, Guilin University of Technology, Guilin 541004, China

Corresponding author: DING Guo-Hua,
Received Date: 22 December 2014
Available Online: 14 February 2015
Fund Project: Supported by the NNSFC (No.2116606) (No.2116606)Guangxi Postgraduate Innovative Research Project (No.YCSZ2014155) (No.YCSZ2014155)

The ligand ethylenediamine-3,5-dichloro salicylaldehyde (HS) and its crystal Co(II) complex (MS) were yielded. The compounds have been characterized on the basis of elemental analysis, IR and 1H NMR spectral studies. X-ray single-crystal diffraction of crystal MS1 showed a classical Salen-N₂O₂ tetrahedral coordination model, space group P1 with a=25.73(2), b=9.899(9), c=6.753(6) Å, β=103.467(10)°, V=1673(3) Å³, Z=4, C₁₆H₁₀C_l4CoN₂O₂, M_r=462.99, D_c=1.838 g/cm³, F(000)=924, µ(MoKα)=1.678 mm^-1 (λ=0.71073 Å), R=0.0275 and wR=0.0567 for 1247 observed reflections with I>2σ(I). Furthermore, luminescent properties were evaluated by UV-Visible absorption and FL spectra. Meanwhile, the thermal stability of compound HS was investigated. TG-DTG showed that the decomposition temperature (Td) of the molecules is up to 256℃ and the compound has fine performance in thermal stability. The results also indicated that the target compound HS exhibited certain chemiluminescence properties under the conditions of different time of 365 nm UV light and different temperature. In general, this kind of multi-functional compounds has potential applications in the fields of information storage and nonlinear optical materials.
- photochromic,
- thermochromic,
- crystal structure
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