Citation: WANG Jian, LIN Ping, DU Shao-Wu. Temperature Dependent Assembly, Structural Diversity and Luminescent Property in Two Novel Cd Coordination Polymers[J]. Chinese Journal of Structural Chemistry, ;2015, 34(6): 945-952. doi: 10.14102/j.cnki.0254-5861.2011-0605 shu

Temperature Dependent Assembly, Structural Diversity and Luminescent Property in Two Novel Cd Coordination Polymers

1.
a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China;
2.
b Graduate University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: LIN Ping,
Received Date: 15 December 2014
Available Online: 6 March 2015
Fund Project: This work was supported by the National Basic Research Program of China (973 Program, 2012CB821702) (973 Program, 2012CB821702)

Temperature dependent assembly of two novel Cd coordination polymers with the phen and H₂MIP ligands (phen=1,10-phenanthrolion and H₂MIP=5-methyl-isophthalic acid), formulated as Cd₂(MIP)₂(phen)₂ (1) and Cd₃(MIP)₃(H₂MIP)(phen)₂ (2). They have been structurally characterized by single-crystal X-ray diffraction, elemental analysis, FT-IR spectra and TGA. 1 crystallizes in the monoclinic space group P2/n, while 2 crystallizes in the triclinic space group P1. 1 shows a 2D (two-dimensional) plane and 2 shows a 1D (one-dimensional) chain. In addition, their solid-state luminescent properties have also been investigated.
- temperature dependent assembly,
- 2D,
- 1D,
- luminescent
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