Citation: LI Ke, LI Shu-Jing, YAO Xin-Jian, NIU Jing-Jing, QIU Xiao-Yang. Syntheses, Crystal Structures and Antimicrobial Activities of Vanadium(V) Complexes with Similar Tridentate Hydrazone Ligands[J]. Chinese Journal of Structural Chemistry, ;2015, 34(6): 885-893. doi: 10.14102/j.cnki.0254-5861.2011-0593 shu

Syntheses, Crystal Structures and Antimicrobial Activities of Vanadium(V) Complexes with Similar Tridentate Hydrazone Ligands

1.
a School of Chemistry & Chemical Engineering, Zhoukou Normal University, Zhoukou 466000, China;
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b Department of Chemistry, Shangqiu Normal University, Shangqiu 476000, China

Corresponding author: LI Shu-Jing,
Received Date: 3 December 2014
Available Online: 9 April 2015
Fund Project: We thank the Educational Commission of Henan Province (No.14B150036) (No.14B150036) the Natural Science Foundation of Henan Province (No.142300410252) (No.142300410252)

Two hydrazone ligands (E)-N'-(2-hydroxy-5-methoxybenzylidene)-2-hydroxybenzohydrazide (HLa) and (E)-N'-(3,5-dichloro-2-hydroxybenzylidene)-4-methoxybenzohydrazide (HLb) were prepared and characterized by IR, UV-Vis and 1H NMR spectra. Based on the hydrazone ligands, two new structurally similar vanadium(V) complexes, [VOL^aL]·CH₃OH (1) and [VOL^bL] (2), where L is the monoanionic form of benzohydroxamic acid (HL), were prepared and characterized by IR and UV-Vis spectra, and single-crystal X-ray diffraction. Complex 1 crystallizes as the monoclinic space group P2₁/n, with a=7.5208(10), b=15.490(2), c=20.8929(18) Å, β=96.373(2)°, V=2418.9(5) Å³, Z=4, R=0.0831, wR=0.2607 and GOOF=1.061. Complex 2 crystallizes as the monoclinic space group P2₁/c, with a=11.8577(18), b=16.468(2), c=12.2288(18) Å, β=106.064(2)°, V=2294.7(6) Å³, Z=4, R=0.0741, wR=0.1745 and GOOF=1.014. X-ray analysis indicates that the complexes are mononuclear vanadium (V) species, with the V atoms located in the octahedral coordination. The hydrazone ligands and the complexes were evaluated for their antibacterial (Bacillus subtilis, Staphylococcus aureus, Escherichia coli, and Pseudomonas fluorescence) and antifungal (Candida albicans and Aspergillus niger) activities by MTT (3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyl tetrazolium bromide) method.
- hydrazone,
- vanadium complex,
- mononuclear complex,
- crystal structure,
- antimicrobial activity
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