Citation: ZHOU Jie, JIANG Bo, LIU Sai, MA Chun, HU Jin-Song. A Novel 2D→3D Network with the Coexistence of Polythreading and Inclined Polycatenation Constructed by the Tripodal Linker[J]. Chinese Journal of Structural Chemistry, ;2015, 34(4): 536-542. doi: 10.14102/j.cnki.0254-5861.2011-0591 shu

A Novel 2D→3D Network with the Coexistence of Polythreading and Inclined Polycatenation Constructed by the Tripodal Linker

ZHOU Jie ^a ,
JIANG Bo ^a ,
LIU Sai ^a ,
MA Chun ^a ,
HU Jin-Song ^a,b,,

a.
a. School of Chemical Engineering, Anhui University of Science and Technology, Huainan 232001, China;
b.
b. State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, China

Corresponding author: HU Jin-Song,
Received Date: 2 December 2014
Available Online: 30 January 2015
Fund Project: Supported by the National Natural Science Foundation of China (21301005) (21301005)the Natural Science Foundation of Anhui Province (1408085QB31) (1408085QB31)

A new cadmium(Ⅱ) coordination polymer with unique structure was synthesized under diffusion process by employing triangular N-containing ligand tris(4-(pyridyl) phenyl) amine (Tppa). Complex 1 crystallizes in the space group Pbcn, with a=28.906(3), b=13.5294(14), c=17.8727(18)Å, V=6989.7(12)Å³, C₆₆H₄₈CdCl₂N₈, M_r=1136.42, D_c=1.080 g/cm³, F(000)=2328, μ=0.428 mm^-1 and Z=4. Complex 1 features a 2D→3D framework with the coexistence of inclined polycatenation and polythreading. In addition, the luminescent property of complex 1 was studied.
- coordination polymer,
- polycatenation,
- polythreading,
- photoluminescent
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