Citation: GONG Ya-Qiong, MI Tao-Qing, JIANG Fei-Long. Synthesis, Crystal Structure and Photoluminescence of a Zn(Ⅱ) Coordination Polymer Derived from 1,1'-Biphenyl-2,2',6,6'-tetracarboxylic Acid[J]. Chinese Journal of Structural Chemistry, ;2015, 34(7): 1087-1091. doi: 10.14102/j.cnki.0254-5861.2011-0587 shu

Synthesis, Crystal Structure and Photoluminescence of a Zn(Ⅱ) Coordination Polymer Derived from 1,1'-Biphenyl-2,2',6,6'-tetracarboxylic Acid

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a. Industry and Ecology Institute, North University of China, Taiyuan 03005a. China;
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b. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Received Date: 1 December 2014
Available Online: 11 May 2015
Fund Project: This work was supported by the Natural Science Foundation of Shanxi Province (2012021005-2) (2012021005-2)

A new polymeric znic(Ⅱ) coordination polymer, [Zn₂(bptc)·(H₂O)₄]_n·nCH₃OH 1, was synthesized by the hydrothermal reaction of Zn(NO₃)₂·6H₂O with 1,1'-biphenyl-2,2',6,6'-tetracarboxylic acid (H₄bptc) and structurally characterized by single-crystal diffraction, IR and elemental analysis. The polymer crystallizes in the orthorhombic system, space group Pnna with a=13.411(1), b=16.418(2), c=9.178(7)Å, V=2025.2(3)Å³, Z=4, C₁₇H₁₄O₁₃Zn₂, M_r=557.06, D_c=1.827 g/cm³, F(000)=1120, μ(MoKα)=2.439 mm^-1. The final R and wR are 0.0548 and 0.1691 for 1279 observed reflections with I>2σ(I). In this compound, the bptc^4- anion adopts monodentate bridging coordination modes connecting the zinc(Ⅱ) ions to form a 1D chain structure, which furnishes a 2D supramolecular architecture through hydrogen bonding interactions formed by carboxylic oxygen atoms of bpdc, oxygen atoms of crystalline methanol and water molecules. Complex 1 displays an emissive maximum at 435 nm in the solid state at room temperature.
- zinc(Ⅱ),
- coordination polymer,
- luminescence,
- crystal structure
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