Citation: OU Guang-Chuan, LI Wen-Yi, YUAN Xian-You, LI Zhi-Zhang. Syntheses and Structures of Two Macrocyclic Nickel(II) Complexes Bridging Benzene Polycarboxylic Acid[J]. Chinese Journal of Structural Chemistry, ;2015, 34(5): 749-756. doi: 10.14102/j.cnki.0254-5861.2011-0585 shu

Syntheses and Structures of Two Macrocyclic Nickel(II) Complexes Bridging Benzene Polycarboxylic Acid

1.
Department of Biology and Chemistry, Hunan University of Science and Engineering, Yongzhou, Hunan 425199, China

Received Date: 28 November 2014
Available Online: 9 March 2015
Fund Project: This work was supported by the Natural Science Foundation of Hunan Province (2015JJ2072) (2015JJ2072) the Key Laboratory of Comprehensive Utilization of Advantage Plants Resources in Hunan South (XNZW14C08) (XNZW14C08) the Construct Program of the Key Discipline in Hunan Province (2011-76) (2011-76)

Two complexes with formulas [NiL][(NiL)(IPA)₂]·8H₂O (1) and [(NiL)(H₂O)₂] [(NiL)(PMA)]·4H₂O (2) (L=5,5,7,12,12,14-hexamethyl-1,4,8,11- tetraazacyclotetradecane, IPA^2-=isophthalic anion, PMA^4-=1,2,4,5-benzenetetracarboxylic anion) were synthesized and characterized by elemental analyses and IR spectra. The crystal structures were determined by X-ray diffraction. In complex 1, the [NiL]²⁺ bridged IPA^2- to give [(NiL)(IPA)₂]^2- monomer, and the [NiL]²⁺ bridged PMA^4- to form a one-dimensional chain [(NiL)(PMA)]_n^2n- in complex 2. The [NiL]²⁺ and [(NiL)(IPA)₂]^2-/[(NiL)(PMA)]^2- are connected through intermolecular hydrogen bonding to generate three-dimensional supramolecular structures.
- macrocyclic nickel(II) complexes,
- isophthalic,
- 1,2,4,5-benzenetetracarboxylic
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