Citation: YANG E, LIN Li-Xiang, DING Qing-Rong, LIN Zheng-Huan, LING Qi-Dan. Synthesis and Characterization of a New Metal-organic Framework with Nou Topology[J]. Chinese Journal of Structural Chemistry, ;2015, 34(6): 894-898. doi: 10.14102/j.cnki.0254-5861.2011-0572 shu

Synthesis and Characterization of a New Metal-organic Framework with Nou Topology

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a College of Materials Science & Engineering, Fujian Normal University, Fuzhou 350007, China;
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b College of Chemistry & Chemistry Engineering, Fujian Normal University, Fuzhou 350007, China;
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c State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, the Chinese Academy of Sciences, Fuzhou 350002, China

Received Date: 17 November 2014
Available Online: 14 March 2015
Fund Project: and Program for Innovative Research Team in Science and Technology in Fujian Province University (IRTSTFJ) (FJSDJK2012063)

A new compound, [H₂N(CH₃)₂]₂[Zn(btec)].H₂O (1, H₄btec=1,2,4,5-benzenetetracarboxylic acid) has been solvothermally synthesized and structurally characterized by singlecrystal X-ray diffraction. The crystal structure is of monoclinic, space group P2₁/c with a=9.5741(3), b=14.5044(4), c=13.7329(5) Å, β=100.582(4)°, V=1874.61(10) Å³, C₁₄H₂0N₂O₉Zn, M_r=425.7, Z=4, D_c=1.387 g/cm³, μ=1.349 mm^-1, F(000)=776, R=0.0560 and wR=0.1684 for 2834 observed reflections (I>2σ(I)). Compound 1 based on μ4-btec and tetrahedral building unit features a three-dimensional (3D) anionic framework with mixed connected nou topology. The luminescent property and thermogravimetric analysis of compound 1 are investigated.
- solvothermal synthesis,
- crystal structure,
- topology,
- metal organic framework
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