Citation: SUN Xiao-Fei, YOU Jun-Ming, XU Xia-Hong, LI Xiao-Ju. A Zn(Ⅱ) Metal-organic Framework Consisting of Hexagonal Cavities Constructed by Benzyl-functionalized 5-Aminoisophthalate[J]. Chinese Journal of Structural Chemistry, ;2015, 34(4): 562-568. doi: 10.14102/j.cnki.0254-5861.2011-0571 shu

A Zn(Ⅱ) Metal-organic Framework Consisting of Hexagonal Cavities Constructed by Benzyl-functionalized 5-Aminoisophthalate

a.
a. College of Chemistry and Chemical Engineering, Fujian Normal University, Fuzhou 350007, China;
b.
b. Fujian Key Laboratory of Polymer Materials, College of Materials Science and Engineering Fujian Normal University, Fuzhou 350007, China

Corresponding author: LI Xiao-Ju,
Received Date: 14 November 2014
Available Online: 28 January 2015
Fund Project: Supported by the Natural Science Foundation of Fujian Province (2010J05017) (2010J05017)Provincial Education Department of Fujian (JA12070) (JA12070)

The hydrothermal reaction of 5-benzylaminoisophthalic acid (H₂BAIP) and Zn(CH₃COO)₂×2H₂O in the presence of NaOH gave rise to a three-dimensional (3-D) metal-organic framework containing Zn(Ⅱ)-carboxylate chains, [Zn(BAIP)]_n. Single-crystal X-ray diffraction analysis reveals that the complex crystallizes in trigonal space group R-3 with a=28.354(2), b=28.354(2), c=8.3821(8)Å, γ=120°, V=5836.0(10)Å³, Z=18, M_r=334.62, D_c=1.714 g×cm^-3, μ=1.909 mm^-1, S=1.162, F(000)=3060, the final R=0.0785 and wR=0.1121 for 2334 observed reflections (I>2σ(I)). Zn(Ⅱ) is in a distorted tetrahedral geometry, and BAIP serves as a μ₄-bridge using two μ₂,η²-bridging carboxylate groups. BAIP links Zn(Ⅱ) ions into a 3-D network containing hexagonal cavities. The coordination-inert benzyl occupies the void space of the large hexagonal cavities. The complex is thermally stable up to 410℃, and exhibits photoluminescent emission at 522 nm on 402 nm excitation.
- carboxylate ligand,
- coordination polymer,
- crystal structure,
- photoluminescence,
- zinc
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