Citation: WANG Hao, LIU Yang, CHEN Fei, GUO Yu-Meng, ZHANG Ying-Hui. Two New Main Group Metal Coordination Polymers Based on 2,5-Furandicarboxylic Acid: Syntheses and Crystal Structures[J]. Chinese Journal of Structural Chemistry, ;2015, 34(4): 585-593. doi: 10.14102/j.cnki.0254-5861.2011-0555 shu

Two New Main Group Metal Coordination Polymers Based on 2,5-Furandicarboxylic Acid: Syntheses and Crystal Structures

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a. Beijing Key Lab of Special Elastomer Composite Materials, College of Materials Science and Engineering, Beijing Institute of Petrochemical Technology, Beijing 102617, China;
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b. College of Chemistry, Key Laboratory Advanced Energy Materials Chemistry(Ministry of Education), Nankai University, Tianjin 300071, China

Received Date: 3 November 2014
Available Online: 22 December 2014
Fund Project:

By using solvothermal method, two new main group metal coordination polymers based on 2,5-furandicarboxylic acid (H₂FDA) ligand, [Sr₂(FDA)₂(H₂O)₅]_n (1) and [Ba₄(FDA)₄(H₂O)₁₀]_n (2), were produced and characterized by single-crystal X-ray diffraction analyses, elemental analyses, IR, and powder X-ray diffraction. Compound 1 crystallizes in monoclinic, space group C2/c with a=13.454(3), b=13.426(3), c=20.166(4)Å, β=107.06(3)°, V=3482.4(13)Å³, D_c=2.188 g/cm³, C₁₂H₁₄Sr₂O₁₅, M_r=573.47, F(000)=2256, μ(MoKα)=6.21 mm^-1, Z=8, R=0.0522 and wR=0.1229 for 2493 observed reflections (I>2σ(I)), and R=0.0689 and wR=0.1324 for all data. Compound 2 crystallizes in triclinic, space group P1 with a=6.8382(14), b=10.932(2), c=25.571(5)Å, α=94.64(3), β=95.41(3), γ=107.83(3)°, V=1799.4(6)Å³, D_c=2.484 g/cm³, C₂₄H₂₈Ba₄O₃₀, M_r=1345.82, F(000)=1272, μ(MoKα)=4.43 mm^-1, Z=2, R=0.0485 and wR=0.0906 for 5020 observed reflections (I>2σ(I)), and R=0.0706 and wR=0.0991 for all data. In 1, the trinuclear clusters Sr₃ are connected with adjacent four clusters by a carboxylate group to produce a two-dimensional (2D) sheet, which is extended by a FDA-based pillar into a 3D framework. In 2, neighbouring trinuclear clusters Ba₃ are linked through two -O-C-O- of FDA^2- ligands to form one-dimensional (1D) chains, which are connected by a FDA-based pillar to construct a 2D framework. The thermal stabilities of 1 and 2 are also investigated.
- 2,5-furandicarboxylic acid,
- main group,
- crystal structure
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