Citation: KONG Zhi-Guo, WANG Wei, BI Hui-Ying, HAN Qian, HE Gui-Yuan, LI Fang-Yuan. A New Two-dimensional Cadmium(II) Coordination Polymer Constructed by 1,10- Phenanthroline Derivative and Flexible Dicarboxylate: Syntheses, Structure, Thermal Behavior and Luminescence[J]. Chinese Journal of Structural Chemistry, ;2015, 34(5): 719-724. doi: 10.14102/j.cnki.0254-5861.2011-0544 shu

A New Two-dimensional Cadmium(II) Coordination Polymer Constructed by 1,10- Phenanthroline Derivative and Flexible Dicarboxylate: Syntheses, Structure, Thermal Behavior and Luminescence

KONG Zhi-Guo ^a,b,, ,
WANG Wei ^a,b ,
BI Hui-Ying ^a,b ,
HAN Qian ^a,b ,
HE Gui-Yuan ^a,b ,
LI Fang-Yuan ^a,b

1.
a Key Laboratory of Preparation and Applications of Environmental Friendly Materials, Jilin Normal University, Ministry of Education, Siping 136000, China;
2.
b Department of Chemistry, Jilin Normal University, Siping 136000, China

Corresponding author: KONG Zhi-Guo,
Received Date: 24 October 2014
Available Online: 26 January 2015
Fund Project: Supported by the Institute Foundation of Siping City (No.2013036) (No.2013036)

In this work, a new two-dimensional Cd(II) coordination polymer, [Cd₃(L)₂(cis-1,4- chdc)₂(trans-1,4-chdc)] (1, L=11-fluoro-dipyrido[3,2-a:2',3'-c]phenazine and 1,4-H₂chdc=1,4- cyclohexanedicarboxylatic acid), has been prepared under hydrothermal conditions. It crystallizes in triclinic, space group P1 with a=8.6951(8), b=10.8362(9), c=14.9445(13) Å, α=76.443(2), β=81.8670(10), γ=82.0640(10)°, V=1347.0(2) Å³, Z=1, C₆₀H₄₈Cd₃F₂N₈O₁₂, M_r=1448.26, D_c=1.785 g/cm³, F(000)=722, μ(MoKa)=1.255 mm^-1, R=0.0333 and wR=0.0790. The 1,4-chdc^2- carboxylates bridge the Cd(II) cations to form a tri-nuclear Cd(II) cluster, which are held together by the cis-1,4-chdc^2- ligands to generate a double-stranded chain. Further, the trans-1,4-chdc^2- ligands bridge adjacent double-stranded chains to yield an interesting two-dimensional network. The π-π interactions among L ligands of neighboring networks result in an interesting three-dimensional supramolecular architecture. In addition, the thermal behavior and luminescent property of 1 have been studied.
- crystal structure,
- coordination polymer,
- 11-fluoro-dipyrido[3,2-a:2',3'-c]phenazine,
- 1,4-cyclohexanedicarboxylatic acid
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