Citation: HAN Min-Le, LING Xun-Li, CHANG Xin-Hong, LIU Guang-Zhen, DU De-Guang. Syntheses, Structures and Characteristics of Two New Cu(Ⅱ) Coordination Polymers Based on 4-tert-butyl-phthalate and Different Bis(1,2,4-triazol-1-yl) Co-Ligands[J]. Chinese Journal of Structural Chemistry, ;2015, 34(4): 543-550. doi: 10.14102/j.cnki.0254-5861.2011-0537 shu

Syntheses, Structures and Characteristics of Two New Cu(Ⅱ) Coordination Polymers Based on 4-tert-butyl-phthalate and Different Bis(1,2,4-triazol-1-yl) Co-Ligands

a.
a. College of Chemistry and Molecular Engineering, Luoyang Normal University, Luoyang 471022, China;
b.
b. Henan Huier Nano Technology Co., Ltd., Luoyang 471003, China

Received Date: 16 October 2014
Available Online: 19 January 2015
Fund Project:

Two new Cu(Ⅱ) coordination polymers, [Cu₂(tbph)₂(btb)₂]_n (1) and {[Cu₂(tbph)₂-(bth)₂]·H₂O}_n (2), (H₂tbph=4-tert-butyl-phthalic acid, btb=1,4-bis(1,2,4-triazol-1-yl)butane, bth=1,6-bis(1,2,4-triazol-1-yl)hexane), have been synthesized and characterized by elemental analysis, FT-IR and X-ray single-crystal diffraction. Complex 1 has a 2D sql layer. Complex 2 shows a (3,4)-connected 2D sheet with a (4.6⁴.8)(4.8²) topology. The thermal behavior of the two corresponding complexes has briefly been investigated.
- Cu(Ⅱ) complex,
- crystal structure,
- 4-tert-butyl-phthalic acid,
- 1,4-bis(1,2,4-triazol-1-yl)butane,
- 1,6-bis(1,2,4-triazol-1-yl)hexane
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