Citation: SHU Xu-Gang, WU Chun-Li, WAN Ke, ZHANG Min, WU Xin. Synthesis, Crystal Structure and Spectroscopic Properties of Zn(Ⅱ) with N-carbamylglutamate Ligand[J]. Chinese Journal of Structural Chemistry, ;2015, 34(3): 423-427. doi: 10.14102/j.cnki.0254-5861.2011-0533 shu

Synthesis, Crystal Structure and Spectroscopic Properties of Zn(Ⅱ) with N-carbamylglutamate Ligand

SHU Xu-Gang ^a,, ,
WU Chun-Li ^a ,
WAN Ke ^b ,
ZHANG Min ^b ,
WU Xin ^c

a.
a. Zhongkai University of Agriculture and Engineering, College of Chemistry and Chemical Engineering, Guangzhou 510225, China;
b.
b. Guangdong University of Technology, College of Light Industry and Chemical Engineering, Guangzhou 510006, China;
c.
c. Key Laboratory of Agro-ecological Processes in Subtropical Region, Institute of Subtropical Agriculture, Chinese Academy of Sciences, Changsha 410125, China

Corresponding author: SHU Xu-Gang,
Received Date: 11 October 2014
Available Online: 10 December 2014
Fund Project: Supported by the Chinese Academy of Sciences comprehensive strategic cooperation project of Guangdong Province (2013B09150009, 2013B090900007) (2013B09150009, 2013B090900007)

ZnC₆H₈N₂O₅.H₂O (NCGZn) has been synthesized, and its functional groups present in the title compound were confirmed by elemental analysis, TG and IR spectral studies. Meanwhile, the crystal of NCGZn was obtained by slow evaporation of a saturated aqueous solution at room temperature and confirmed by single-crystal X-ray diffraction analysis. It crystallizes in triclinic, space group P2₁ with a=5.03220(1), b=13.3747(4), c=12.9944(4)Å, β=92.987(2)°, V=873.39(4)Å³, Z=2, C₁₂H₂₀N₄O₁₂Zn₂, M_r=543.10, D_c=2.065 g/cm³, F(000)=552, μ(MoKa)=2.826 mm^-1, R=0.0422 and wR=0.1142. In NCGZn, Zn(1) and the symmetry formed Zn(1) ions are connected by five atoms from four NCG_-2H anions and a water molecule. A NCG ligand has two carboxylate groups, one connecting a Zn ion, and the other bridgiong two Zn ions. The NCG ligand bridges four Zn ions through the amino group and two carboxylate groups with a water molecule to yield a 3D coordination polymer structure with hydrogen bonds.
- N-carbamylglutamate,
- Zn(Ⅱ) complex,
- X-ray diffraction analysis,
- structure
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