Citation: SUN Jie, LI Yan-Min, LIU Yu-Jing, WANG Yan-Hua, ZHOU Ju-Hua. Solvothermal Synthesis, Crystal Structure and Luminescent Properties of a 3D MOF Based on 4,6-Dimethyl-5-nitroisophthalic Acid[J]. Chinese Journal of Structural Chemistry, ;2014, 33(12): 1854-1859. doi: 10.14102/j.cnki.0254-5861.2011-0532 shu

Solvothermal Synthesis, Crystal Structure and Luminescent Properties of a 3D MOF Based on 4,6-Dimethyl-5-nitroisophthalic Acid

1.
School of Life Science, Ludong University, Yantai, Shandong 264025, China

Received Date: 30 May 2014
Available Online: 24 September 2014
Fund Project:

A new 3D metal organic framework, {[Zn₄(dna)₄(dpb)₂(H₂O)₂]·H₂O}_n(1, H₂dna=4,6-dimethyl-5-nitroisophthalic acid; dpb=1,4-bis-(4-pyridyl)-benzene), has been solvothermally synthesized and characterized by TGA, and single-crystal X-ray diffraction. Compound 1 crystalizes in monoclinic, space group P2₁/c with a=15.169(2), b=13.0539(18), c=9.1669(13)Å, C₁₈H₁₇N₂O₈Zn, M_r=454.71, V=1798.9(4)Å³, Z=4, D_c=1.679 g·cm^-3, μ=1.418 mm^-1, F(000)=932, 2.07≤θ≤25.00°, λ(MoKα)=0.71073Å, T=273(2) K, the final R=0.0300, wR=0.0754 and S=1.028. X-ray diffraction analysis reveals that complex 1 possesses a 3D pcu framework constructed by (4,4)-connected 2D layers and dpb linkers. In addition, the solid state luminescent property of complex 1 at room temperature was also investigated.
- crystal structure,
- pcu framework,
- fluorescence
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