Citation: FENG Jian-Hua, WANG Xiao-Feng, ZHANG Zhi-Qiang, WU Gang. Syntheses, Structure and Properties of a Strontium(Ⅱ) Complex with 5-Sulfoisophthalic Acid Monosodium[J]. Chinese Journal of Structural Chemistry, ;2015, 34(3): 428-434. doi: 10.14102/j.cnki.0254-5861.2011-0527 shu

Syntheses, Structure and Properties of a Strontium(Ⅱ) Complex with 5-Sulfoisophthalic Acid Monosodium

a.
a. College of Material and Chemical Engineering, Chuzhou University, Chuzhou, Anhui 239012, China;
b.
b. College of Biochemical & Environmental Engineer, Xiaozhuang University, Nanjing 211171, China

Received Date: 8 October 2014
Available Online: 27 November 2014
Fund Project: his project was supported by the National Natural Science Foundation of China (41472047) (41472047) Science Research Starting Project of Chuzhou University (2014qd035) (2014qd035)

A new Sr(Ⅱ) complex, [Sr(Hsip)(H₂O)] (1, NaH2sip=5-sulfoisophthalic acid monosodium), has been synthesized by solvothermal reaction of SrCO₃ and NaH₂sip at 120℃, and characterized by single-crystal X-ray diffraction studies, elemental analysis and FT-IR. Singlecrystal X-ray diffraction reveals that compound 1 has a 3D architecture, and there is only one crystallographically independent Sr(Ⅱ) ion in 1. The coordination geometry of Sr(Ⅱ) is a distorted tetragonal anti-prism. The whole Hsip^2- ligand performs a μ₆-coordination model. In the solid state, complex 1 shows luminescence with the maximum emission intensity at 417 nm upon excitation at 320 nm. Thermal stability of complex 1 was also investigated.
- Sr(Ⅱ) complex,
- sulfonate group,
- luminescence property,
- thermal stability
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