Citation: ZHANG Xing-Jing, WANG Lu-Yao, WEI Bing, ZHANG Wen-Tong, CHE Guang-Bo. Syntheses, Structures and Photoluminescence of the Cadmium(Ⅱ) and Copper(Ⅱ) Complexes Based on 4'-(4"-Pyridyl)-2,2':6',2"-terpyridine and 1,4-Benzenedicarboxylic Acid Ligands[J]. Chinese Journal of Structural Chemistry, ;2015, 34(7): 1069-1079. doi: 10.14102/j.cnki.0254-5861.2011-0526 shu

Syntheses, Structures and Photoluminescence of the Cadmium(Ⅱ) and Copper(Ⅱ) Complexes Based on 4'-(4"-Pyridyl)-2,2':6',2"-terpyridine and 1,4-Benzenedicarboxylic Acid Ligands

a.
a. College of Chemistry, Jilin Normal University, Siping 136000, China;
b.
b. Key Laboratory of Preparation and Applications of Environmental Friendly Materials, Jilin Normal University, Siping 136000, China

Received Date: 8 January 2015
Available Online: 27 April 2015
Fund Project: Supported by the Program for New Century Excellent Talents in University (NCET-10-0176) (NCET-10-0176) the Natural Science Foundation of Jilin Province (No. 20130521019JH) (No. 20130521019JH)

Two new metal-organic complexes [Cd₂(1,4-BDC)(4-pytyp)(H₂O)₄]·(1,4-BDC) (1) and [Cu₂(1,4-BDC)(4-pytyp)₂(H₂O)₂]·(1,4-BDC)·8H₂O (2) (4-pytyp=4'-(4"-pyridyl)-2,2':6',2"-terpyridine, 1,4-H₂BDC=1,4-benzenedicarboxylic acid) have been synthesized under hydrothermal conditions and characterized by elemental analysis, infrared analysis and X-ray single-crystal diffraction. The scrutiny of single-crystal structure reveals that complex 1 forms to a 3D supramolecular network linked by π-π stacking interactions and hydrogen bonds. X-ray diffraction analysis reveals that complex 2 exhibits a 3D supramolecular network linked through complicated hydrogen bonds. The thermogravimetric analysis and photoluminescent properties of 1 and 2 are discussed in detail.
- cadmium(Ⅱ) complex,
- copper(Ⅱ) complex,
- 4'-(4"-pyridyl)-2,2':6',2"-terpyridine,
- 1,4-benzenedicarboxylic acid,
- crystal structure
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