Citation: HU Biao, YU Di, HUANG Kai, YU Shu-Juan. Metal-ion Interactions with Sugars: Crystal Structure of Bis(4-dehydro-L-arabinose) Calcium Methanol Bishydrate[J]. Chinese Journal of Structural Chemistry, ;2015, 34(5): 764-770. doi: 10.14102/j.cnki.0254-5861.2011-0517 shu

Metal-ion Interactions with Sugars: Crystal Structure of Bis(4-dehydro-L-arabinose) Calcium Methanol Bishydrate

1.
College of Light Industry and Food Science, South China University of Technology, Guangzhou, Guangdong 510640, China

Corresponding author: HU Biao,
Received Date: 9 September 2014
Available Online: 16 March 2015
Fund Project:

The crystal structure of the metal-organic frame Ca(C₅H₉O₅)₂·CH₃OH·2H₂O (1) has been synthesized and characterized. Complex 1 belongs to a tetragonal P4₃2₁2 space group. In complex 1, the sugar moiety shows a beta-L configuration of pyranose form. The calcium(II) is eight-coordinated, binding to four such sugar moieties, via O(1), O(2) of two molecules and O(3), O(4) of the other two, with the 4-hydroxy group being deprotonated. The water and methanol molecules are not coordinated to the calcium ion.
- metal-organic framework,
- Ca-L-arabinose complex,
- crystal structure
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