Citation: LIU Jie, WANG Hui, LI Dan-Dan, ZHOU Hong-Ping, TIAN Yu-Peng, WU Jie-Ying. Synthesis, Crystal Structure and Two-photon Absorption Properties of 4'-(N,N-di(4-hydroxymethyl phenyl) amino)phenyl-2,2': 6',2"-terpyridine[J]. Chinese Journal of Structural Chemistry, ;2015, 34(3): 365-372. doi: 10.14102/j.cnki.0254-5861.2011-0503 shu

Synthesis, Crystal Structure and Two-photon Absorption Properties of 4'-(N,N-di(4-hydroxymethyl phenyl) amino)phenyl-2,2': 6',2"-terpyridine

a.
a. Department of Chemistry, Anhui University, Hefei 230039, China;
b.
b. School of Chemistry and Material Engineering, Fuyang Normal College, Fuyang, Anhui 236037, China

Received Date: 9 September 2014
Available Online: 26 November 2014
Fund Project: This project was supported by the National Natural Science Foundation of China (51372003) (51372003) Natural Science Foundation of Anhui Province (1208085MB22) (1208085MB22)

A novel donor-acceptor (D-A) triphenylamino terpyridine derivative Lwas facilely synthesized and fully characterized, and its single crystals were obtained and determined by X-ray diffraction analysis. It crystallizes in triclinic, space group P1 with a=11.760(5), b=12.516(5), c=12.850(5)Å, α=67.141(5), β=65.284(5), γ=75.876(5)°, M_r=621.54, V=1575.6(11)Å³, Z=2, D_c=1.310 g/cm³, μ=0.245 mm^-1, F(000)=648, the final R=0.0671 and wR=0.1869 for 11328 observed reflections with I>2σ(I). Linear and nonlinear optical properties of terpyridine derivative Lwere systematically investigated. The maximum two-photon cross-section of Lwas 382.5 GM (Goeppert-Mayer), measured by two-photon excited fluorescence (TPEF) method. This result demonstrates that the increase of intramolecular charge transfer (ICT) leads to enhanced two-photon absorption (2PA), which could be achieved by introducing additional electron-donor groups to the molecular framework.
- terpyridine derivatives,
- crystal structure,
- photophysical properties,
- two-photon excited fluorescence
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