Citation: KONG Zhi-Guo, GUO Sheng-Nan, ZHOU Xue-Lian, LV Jia-Qi, ZHAO Zhong-Yu. A New Cadmium(Ⅱ) Dimer Constructed by 1,10-Phenanthroline Derivative and Chlorine Anions: Syntheses, Crystal Structure and Photoluminescence[J]. Chinese Journal of Structural Chemistry, ;2015, 34(4): 606-610. doi: 10.14102/j.cnki.0254-5861.2011-0470 shu

A New Cadmium(Ⅱ) Dimer Constructed by 1,10-Phenanthroline Derivative and Chlorine Anions: Syntheses, Crystal Structure and Photoluminescence

KONG Zhi-Guo ^a,b,, ,
GUO Sheng-Nan ^a,b ,
ZHOU Xue-Lian ^a,b ,
LV Jia-Qi ^a,b ,
ZHAO Zhong-Yu ^a,b

a.
a. Key Laboratory of Preparation and Applications of Environmental Friendly Materials, Jilin Normal University, Ministry of Education, Siping 136000, China;
b.
b. Department of Chemistry, Jilin Normal University, Siping 136000, China;
c.
c. School of the Ocean, Harbin Institute of Technology, Weihai 264209, China

Corresponding author: KONG Zhi-Guo,
Received Date: 4 August 2014
Available Online: 26 January 2015
Fund Project:

In this work, a new Cd(Ⅱ) dimeric compound, [Cd(Cl)₂(L)(H₂O)]₂ (1, L=2-(4-fluorophenyl)-1H-imidazo[4,5-f][1,10]phenanthroline), has been achieved under hydrothermal conditions. The structure of compound 1 was determined by single-crystal X-ray diffraction. Compound 1 crystallizes in monoclinic, space group P2₁/c with a=8.944(2), b=18.781(5), c=10.904(3)Å, β=91.392(4)°, V=1831.2(8)Å³, Z=2, CH₂₆Cd₂F₂Cl₄C₁₄N₈O₂, M_r=1031.27, D_c=1.870 g/cm³, F(000)=1016, μ(MoKa)=1.513 mm^-1, R=0.0532 and wR=0.1407. Each Cd(Ⅱ) atom is in an octahedral coordination sphere, completed by two nitrogen atoms from one L ligand, two chlorine anions, and one water oxygen atom. Two chlorine anions bridge two Cd(Ⅱ) atoms to give a dimer [Cd(Cl)₂(L)(H₂O)]₂. Adjacent dimers are stacked by one type of π-π interactions among L ligands to generate a 1D supramolecular chain. Further, the 1D supramolecular chains are stacked by another type of π-π interactions among L ligands to give a 2D supramolecular layer. Finally, the luminescent property of 1 has been studied in solid state at room temperature.
- crystal structure,
- dimer,
- 2-(4-fluorophenyl)-1H-imidazo[4,5-f][1,10]phenanthroline
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