Citation: JIANG Xiu-Rong, TANG Zhi-Wei, XIE Gui-Xiang, DONG Yan, WEN De-Cai. Hydrothermal Syntheses and Crystal Structures of Two Complexes with Cyclic Dimer and 2D Network Structures of 3-Nitrophthalate and N-Donor Ligand[J]. Chinese Journal of Structural Chemistry, ;2015, 34(3): 386-392. doi: 10.14102/j.cnki.0254-5861.2011-0465 shu

Hydrothermal Syntheses and Crystal Structures of Two Complexes with Cyclic Dimer and 2D Network Structures of 3-Nitrophthalate and N-Donor Ligand

1.
College of Chemistry and Materials Science, Longyan University, Longyan 364000, China

Corresponding author: WEN De-Cai,
Received Date: 25 September 2014
Available Online: 30 November 2014
Fund Project: This work was supported by the National Natural Science Foundation of China (21371088) (21371088)the Education Department of Fujian Province (No. JK2012048, JA12310, JB12207) (No. JK2012048, JA12310, JB12207)

Two complexes, [Cd(nphth)(2,2'-bipy)(H₂O)]₂·2H₂O (1) and [Cd(nphth)(4,4'-bipy)(H₂O)]_n (2) (nphth=3-nitrophthalate, 2,2'-bipy=2,2'-bipyridine, 4,4'-bipy=4,4'-bipyridine), were synthesized by hydrothermal reactions and structurally characterized. Complex 1 crystallizes in triclinic with space group P1, a=0.7599(4), b=1.0551(6), c=1.2448(6) nm, α=88.96(2), β=75.40(2), γ=76.76(2)°, V=0.9393(9) nm³, Z=1, D_c=1.816 Mg/m³, F(000)=512, μ=1.217 mm^-1, S=0.946, the final R=0.0238 and wR=0.0631. Complex 2 crystallizes in monoclinic, space group P2₁/c, a=0.737(5), b=2.338(1), c=1.0030(6) nm, β=96.359(9)°, V=1.803(2) nm³, Z=4, D_c=1.826 Mg/m³, F(000)=984, μ=1.260 mm^-1, S=1.016, the final R=0.0455 and wR=0.1007. Complex 1 exhibits a discrete cyclic binuclear structure and complex 2 possesses a 2D layer structure with cyclic binuclear unit. The fluorescent spectrum study shows that complex 1 exhibits fluorescent emission in the solid state at room temperature.
- cadmium complex,
- 3-nitrophthalic acid,
- hydrothermal synthesis,
- crystal structure
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