Citation: YAN Wei-Hong, YANG Li-Bin, SHEN Ming-Le, JI E-Yu. A Three-dimensional Ba(Ⅱ) Coordination Polymer Based on H₄AQTC (Anthraquinone-1,4,5,8-tetracarboxylic Acid): Quinone Oxygen Atoms Participate in Coordination[J]. Chinese Journal of Structural Chemistry, ;2015, 34(1): 133-139. doi: 10.14102/j.cnki.0254-5861.2011-0430 shu

A Three-dimensional Ba(Ⅱ) Coordination Polymer Based on H₄AQTC (Anthraquinone-1,4,5,8-tetracarboxylic Acid): Quinone Oxygen Atoms Participate in Coordination

1.
Nanyang Key Laboratory of Industrial Microbiology, School of Biology and Chemistry Engineering, Nanyang Institute of Technology, Nanyang 473004, China

Corresponding author: YAN Wei-Hong,
Received Date: 23 June 2014
Available Online: 4 September 2014
Fund Project:

A novel coordination polymer [Ba₂(AQTC)(H₂O)₃]_n (1, H₄AQTC=anthraquinone-1,4,5,8-tetracarboxylic acid) has been prepared under hydrothermal conditions and characterized by single-crystal X-ray diffraction, elemental analysis, infrared spectroscopy and thermogravimetric analysis. Two quinone oxygen atoms and all carboxylate oxygen atoms of AQTC^4- are involved in coordination. Two equivalent barium ions are mainly linked by carboxylate oxygen atoms into a dimer. Neighbouring dimers are further connected by the AQTC^4- ligand through carboxylate oxygen atom, leading to a 1-D chain structure. Every two adjacent chains are mainly further connected by face carboxylate oxygen atoms and water molecule, generating a two-dimensional layer structure. Such 2-D layer structures are connected with O(6) and O(6C) atoms from water molecules to form a 3-D structure. In addition, luminescent properties of 1 are also investigated.
- anthraquinone-1,4,5,8-tetracarboxylic acid,
- crystal structure,
- quinone oxygen
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