Citation: HUANG Deng-Deng, PAN Qi-Jian, DAN Yuan-Yuan, CHEN Li-Zhuang. Hydrothermal Syntheses, Crystal Structures, TGA and Electrochemistry Properties of Two Metal-organic Coordination Compounds Based on 4'-((1H-1,2,4-triazol-1-yl)methyl)-[1,1'-biphenyl]-2-carbonitril[J]. Chinese Journal of Structural Chemistry, ;2015, 34(1): 123-132. doi: 10.14102/j.cnki.0254-5861.2011-0428 shu

Hydrothermal Syntheses, Crystal Structures, TGA and Electrochemistry Properties of Two Metal-organic Coordination Compounds Based on 4'-((1H-1,2,4-triazol-1-yl)methyl)-[1,1'-biphenyl]-2-carbonitril

1.
School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, China

Corresponding author: DAN Yuan-Yuan, CHEN Li-Zhuang,
Received Date: 23 June 2014
Available Online: 21 August 2014
Fund Project: Supported by the National Natural Science Foundation of China (No. 21201087) (No. 21201087) the Qing Lan Project of Jiangsu Province and Jiangsu Overseas Research & Training Program for University Prominent Young & Middle-aged Teacher and Presidents, the Innovation Program of Graduate Students in Jiangsu Province (SJZZ-0142) (11KJB150004)

Two novel metal-organic coordination compounds with molecular structures of {[Co(TMBC)₄Cl₂]·2H₂O} (1) and {[Ni(TMBC)₄Cl₂]·2H₂O} (2) (TMBC=4'-((1H-1,2,4-triazol-1-yl)methyl)-[1,1'-biphenyl]-2-carbonitrile), have been synthesized under hydrothermal conditions of CoCl₂·6H₂O and NiCl₂·6H₂O with 4'-((1H-1,2,4-triazol-1-yl)methyl)-[1,1'-biphenyl]-2-carbonitrile, respectively. Both compounds crystallize in triclinic systems, space group P1. They are characterized by single-crystal X-ray diffraction analysis, elemental analysis, IR spectroscopy and TGA. Moreover, their electrochemical behaviors have also been studied in different electrolyte solutions, respectively.
- cobalt,
- nickel,
- hydrothermal condition,
- crystal structure,
- electrochemical properties
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