Citation: NIE Xu-Liang, HU Chun-Yan, HUANG Chang-Gan, SHANG-GUAN Xin-Chen. Synthesis and Crystal Structure of a Three-dimensional Cobalt Coordination Polymer Assembled by Ozagrel Ligands[J]. Chinese Journal of Structural Chemistry, ;2015, 34(1): 117-122. doi: 10.14102/j.cnki.0254-5861.2011-0419 shu

Synthesis and Crystal Structure of a Three-dimensional Cobalt Coordination Polymer Assembled by Ozagrel Ligands

a.
a. Key Laboratory of Natural Product Research and Development, Nanchang 330045, China;
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b. College of Science, Jiangxi Agricultural University, Nanchang 330045, China

Corresponding author: SHANG-GUAN Xin-Chen,
Received Date: 17 June 2014
Available Online: 15 October 2014
Fund Project: This work was supported by the National Natural Foundation of China (No. 31060213) (No. 31060213)the Research Foundation of Educational Department of Jiangxi Province (No. GJJ13261) (No. GJJ13261)

A three-dimensional cobalt coordination polymer [Co(IMPAA)₂]_n (1, HIMPAA=(2E)-3-[4-(1H-imidazol-1-ylmethyl)phenyl]acrylic acid) was synthesized with ozagrel and structurally characterized by element analysis, IR, PXRD, TGA and X-ray diffraction. Complex 1 is of monoclinic system, space group P2₁ with a=5.136(4), b=25.577(19), c=8.174(6)Å, V=1078.6(14)Å³, M_r=513.41, Z=2, D_c=1.581 g/cm³, F(000)=686, μ=0.840 mm^-1, S=1.119, R_int=0.0637 and wR=0.1456. In complex 1, four IMPAA^- and four Co(Ⅱ) ions form a S-shaped 52-membered macrocycle [Co₄(IMPAA)₄]⁴⁺. Two carboxlate oxygen atoms link the macrocycles to form a one-dimensional chain. IMPAA^- ligands bridge one-dimensional chains to yield a novel three-dimensional metal-organic framework (MOFs). The complex is stable up to 350℃.
- coordination polymer,
- crystal structure,
- ozagrel,
- Co(Ⅱ),
- TGA properties
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