Citation: XIN Ling-Yun, LI Gui-Lian, LI Xiao-Ling, LIU Guang-Zhen, ZHANG Xue. One-dimensional Coordination Polymers Assembled into Two Supramolecular Frameworks with High Stability[J]. Chinese Journal of Structural Chemistry, ;2015, 34(1): 110-116. doi: 10.14102/j.cnki.0254-5861.2011-0413 shu

One-dimensional Coordination Polymers Assembled into Two Supramolecular Frameworks with High Stability

1.
College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471022, China

Received Date: 6 June 2014
Available Online: 9 October 2014
Fund Project: This work was supported by the National Natural Science Foundation of China (No. 21271098) (No. 21271098)the Foundation of Education Committee of Henan Province (No. 142300410301) (No. 142300410301)

The dual ligand system of V-shaped 5-(4-carboxy-2-nitrophenoxy)-isophthalic acid (Hcn-H₂ipa) and dipyridy-type molecules produces two new coordination polymers: {[Ni(cn-Hipa)(bpa)(H₂O)₃]·1.5H₂O}_n 1 and {[Cu(Hcn-ipa)(ppe)₂]}_n 2 (bpa=1,2-bis(4-pyrid-yl)ethane, and ppe=trans-1-(2-pyridyl)-2-(4-pyridyl)ethylene). Two complexes have been characterized by single-crystal X-ray diffraction, elemental analysis, IR, and thermogravimetric analysis (TGA). Complex 1 is of monoclinic system, space group C2 with a=25.936(3), b=7.6100(10), c=16.558(2)Å, β=105.9470(10)°, V=3142.4(7)Å³, D_c=1.415 g/cm³, M_r=669.23, Z=4, F(000)=1388, μ=0.687 mm^-1, the final R=0.0397 and wR=0.0967 for 12070 observed reflections with I>2σ(I). Complex 2 belongs to the triclinic system, space group P1 with a=10.165(5), b=14.946(7), c=15.506(11)Å, α=106.461(7), β=102.454(8), γ=107.861(5)°, V=2029(2)Å³, D_c=1.266 g/cm³, M_r=773.20, Z=2, F(000)=794, μ=0.595 mm^-1, the final R=0.0538 and wR=0.1378 for 15488 observed reflections with I>2σ(I). Two complexes show that the 1D polymeric chains are cohered together by extensive H-bonds to complete stable supramolecular microporous frameworks.
- supramolecular structures,
- coordination polymers,
- thermal stabilities
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