Citation: WANG Hong-Sheng, LI Xue-Feng, XIA Jun. Synthesis, Structure and Near-infrared Photoluminescent Property of a Tetranuclear Er(Ⅲ) Complex[J]. Chinese Journal of Structural Chemistry, ;2015, 34(1): 87-94. doi: 10.14102/j.cnki.0254-5861.2011-0403 shu

Synthesis, Structure and Near-infrared Photoluminescent Property of a Tetranuclear Er(Ⅲ) Complex

a.
a. School of Chemistry and Chemical Engineering, Xuchang University, Xuchang, Henan 461000, China;
b.
b. Department of Chemistry, Nankai University, Tianjin 300071, China

Received Date: 5 June 2014
Available Online: 12 September 2014
Fund Project:

A tetranuclear erbium complex with pyridine-2,4,6-tricarboxylic acid (H₃ptc), [Er₄(ptc)₄(H₂O)₁₈]·6H₂O (1), has been synthesized by hydrothermal method. The complex crystallizes in triclinic system, space group P1, with a=7.620(2), b=10.459(3), c=17.418(5)Å, α=92.351(5), β=92.080(5), γ=95.627(4)°, V=1379.1(7)Å³ and Z=2. One Er(Ⅲ) cation is eight-coordinated and the other is nine-coordinated. The complex exhibits characteristic luminescence of erbium cation in near-infrared region upon the excitation of UV-rays. Furthermore, a three-dimensional supramolecular complex was formed by weak hydrogen bonds among the tetranuclear units.
- pyridine-2,4,6-tricarboxylic acid,
- photoluminescence,
- near infrared,
- erbium
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