Citation: LI Ming-Tian, FU Qing-Shan, ZENG Xian-Guang, YANG Rui-Song, WANG Cheng-Gang. Synthesis, Characterization and Thermostability of a Novel Pb(Ⅱ) Coordination Polymer with Mixed Ligands[J]. Chinese Journal of Structural Chemistry, ;2015, 34(1): 154-160. doi: 10.14102/j.cnki.0254-5861.2011-0391 shu

Synthesis, Characterization and Thermostability of a Novel Pb(Ⅱ) Coordination Polymer with Mixed Ligands

a.
a. College of Materials and Chemical Engineering, Sichuan University of Science and Engineering, Zigong 643000, China;
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b. Material Corrosion and Protection Key Laboratory of Sichuan Province, Zigong 643000, China;
c.
c. College of Chemistry, Central China Normal University, Wuhan 430079, China

Corresponding author: LI Ming-Tian,
Received Date: 28 May 2014
Available Online: 21 August 2014
Fund Project: Supported by the National Natural Science Foundation of China (No. 51303115) (No. 51303115)Natural Science Foundation of Sichuan University of Science and Engineering (No. 2013RC03) (No. 2013CL08)

A novel mixed-ligand coordination polymer [Pb(phen)(NNDS)(H₂O)]_n·nH₂O (1) was obtained from the reaction of 1,10-phenanthroine (phen), Pb(OAc)₂ and sodium 1-nitroso-2-naphthol-3,6-disulfonate (Na₂NNDS) in a mixed solvent. The complex was characterized by elemental analysis, IR and X-ray single-crystal diffraction. Crystal data for 1: monoclinic, space group P2₁/c, a=11.5835(9), b=14.6334(11), c=13.9030(11)Å, β=98.4180(10)°, V=2331.3(3)Å³, Z=4, M_r=754.70, D_c=2.150 mg/m³, μ=7.483 mm^-1, F(000)=1456, the final R=0.0430 and wR=0.0841 for 4221 observed reflections with I>2σ(I). The Pb(Ⅱ) center is coordinated by six O and two N atoms showing a distorted dodecahedron configuration. The multidentate ligand of NNDS dianion exhibits peculiar coordination mode, and the two O atoms of two sulfonate anions bridge two Pb(Ⅱ) cations into a dimer, and the O atom of nitroso group links the other dimer into 2D sheets extending in the [011] plane. There exist significant π-π stacking interactions between adjacent phen and NNDS. The 3D network is formed by 2D sheets interlinked by hydrogen bonds and π-π stacking interactions. The thermostability of 1 was investigated by TG and DSC.
- organosulfonate complex,
- coordination polymer,
- crystal structure,
- thermostability
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