Citation: CHEN Xin, ZHANG Ming-Xing, HUANG Kun-Lin, XIAO Feng, ZHANG Xiao-Ping. A 3-Connected 3D Microporous Metal-organic Framework with Intersected Channels and Rare DEH Topology[J]. Chinese Journal of Structural Chemistry, ;2014, 33(12): 1831-1835. doi: 10.14102/j.cnki.0254-5861.2011-0387 shu

A 3-Connected 3D Microporous Metal-organic Framework with Intersected Channels and Rare DEH Topology

1.
Key Laboratory of Green Synthesis and Applications, College of Chemistry, Chongqing Normal University, Chongqing 401331, China

Corresponding author: HUANG Kun-Lin,
Received Date: 11 September 2014
Available Online: 21 October 2014
Fund Project: Program for Innovation Team Building at Institutions of Higher Education in Chongqing (KJTD201309) (No. KJ100602)

A novel metal-organic coordination polymer {[Cd(mppdc)(H₂O)]·H₂O}_n (1, H₂mppdc=2,6-dimethyl-4-phenylpyridine-3,5-dicarboxylic acid) was synthesized from the reaction of H2mppdc, Cd(NO₃)₂·4H₂O and CH₃OH under solvothermal conditions. The crystal is of tetragonal system, space group I4₁/a, with a=19.109(2), b=19.109(2), c=24.317(7)Å, V=8880(3)Å³, Z=16, M_r=417.68, D_c=1.250 Mg/m³, F(000)=3328, the final R=0.0516 and wR=0.1185 (I>2σ(I)). Complex 1 displays a 3D microporous metal-organic framework with intersected channels and rare (8₂10) DEH topology. The complex exhibits strong photoluminescence at room temperature in the solid state.
- Cd(Ⅱ),
- pyridinedicarboxylate,
- coordination polymer,
- photoluminescence
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