Citation: YANG Rui, GE Ming, VAN HECKE Kristof, CUI Guang-Hua. Synthesis, Crystal Structure and Catalytic Properties of a New 2D Nickel(Ⅱ) Coordination Polymer Based on Flexible Bis(benzimidazole)[J]. Chinese Journal of Structural Chemistry, ;2014, 33(12): 1819-1825. doi: 10.14102/j.cnki.0254-5861.2011-0377 shu

Synthesis, Crystal Structure and Catalytic Properties of a New 2D Nickel(Ⅱ) Coordination Polymer Based on Flexible Bis(benzimidazole)

a.
a. College of Chemical Engineering, Hebei United University, Tangshan, Hebei 063009, China;
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b. Department of Inorganic and Physical Chemistry, Ghent University, Krijgslaan 281 S3, B-9000 Ghent, Belgium

Corresponding author: CUI Guang-Hua,
Received Date: 17 May 2014
Available Online: 19 June 2014
Fund Project: This project was supported by the Starting Research Fund from Hebei United University (35398599) (35398599)the Natural Science Foundation of Hebei Province (B2014209182) (B2014209182)

A new Ni(Ⅱ) coordination polymer [Ni(L)₂(SCN)₂]_n (L=1,4-bis(benzimidazol-1-yl)butane) was synthesized hydrothermally and characterized by elemental analysis, IR spectroscopy and single-crystal X-ray diffraction. The title compound crystallizes in the monoclinic system, space group C2/c with a=9.4760(3), b=24.0408(8), c=16.5871(5)Å, β=99.832(3)°, V=3723.2(2)Å³, Z=4, D_c=1.348 g/cm³, F(000)=1576, the final R=0.0486 and wR=0.0936 for 2938 observed reflections with I>2σ(I) for the complex. Structural analysis shows that the coordination polymer possesses a 2D (4,4) layer structure which is composed of Ni(Ⅱ) centers bridged by L ligand with two kinds of conformations and further assembled into a 3D supramolecular network via π-π stacking interactions. In addition, the fluorescence and catalytic properties, for the degradation of Congo red, of the complex were investigated.
- bis(benzimidazole),
- catalytic property,
- crystal structure,
- Ni(Ⅱ) complex
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