Citation: AAMER SAEED, ULRICH FLÖRKE. Synthesis and Crystal Structure of N-(Biphenyl-2-thiocarbamoyl)-4-(1,3-dichlorophenyl) Carboxamide[J]. Chinese Journal of Structural Chemistry, ;2015, 34(6): 853-857. doi: 10.14102/j.cnki.0254-5861.2010-1479 shu

Synthesis and Crystal Structure of N-(Biphenyl-2-thiocarbamoyl)-4-(1,3-dichlorophenyl) Carboxamide

AAMER SAEED ^a ,
ULRICH FLÖRKE ^b

1.
a Department of Chemistry, Quaid-I-Azam University, Islamabad 45320, Pakistan;
2.
b Department Chemie, Fakultät fur Naturwissenschaften, Universität Paderborn, Warburgerstrasse 100, D-33098 Paderborn, Germany

Received Date: 18 April 2014
Available Online: 30 March 2015

The synthesis of the title molecule was achieved by the reaction of 2,4-dichlorobenzoyl chloride with potassium thiocyanate in 1:1 molar ratio in dry acetonitrile to afford the corresponding isothiocyante in situ followed by the treatment with 2-aminobiphenyl. The structure of the target compound was established by elemental analysis, FTIR, ¹H, ¹³C NMR and mass spectroscopy and unequivocally confirmed by the crystallographic data. The title compound crystallizes in the monoclinic space group P2₁/n with a=13.356(2), b=7.0761(11), c=20.539(3) Å, β=105.723(4)°, V=1868.5(5) Å³ and Z=4.
- synthesis,
- crystal structure,
- N-(biphenyl-2-thiocarbamoyl)-4-(1,3-dichlorophenyl)carboxamide
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