Citation: CAO Cheng, LIU Zhiyu, JI Xiangdong, SHAO Xiaoxiao, XIAO Hong. Highly Selective Recognition of a Long-Chain Alkoxyphenylhydrozone Derivative for Floride Ion[J]. Chinese Journal of Applied Chemistry, ;2020, 37(12): 1432-1440. doi: 10.11944/j.issn.1000-0518.2020.12.200168 shu

Highly Selective Recognition of a Long-Chain Alkoxyphenylhydrozone Derivative for Floride Ion

CAO Cheng ^a,b ,
LIU Zhiyu ^c ,
JI Xiangdong ^a,, ,
SHAO Xiaoxiao ^a ,
XIAO Hong ^a

a.
Key Laboratory of Hexi Corridor Resources Utilization of Gansu, College of Chemistry and Chemical Engineering, Hexi University, Zhangye, Gansu 734000, China
b.
Kaiyuan Bio-Tech Development Center, Hexi University, Zhangye, Gansu 734000, China
c.
Zhangye People's Hospital Affiliated to Hexi University, Hexi University, Zhangye, Gansu 734000, China

Corresponding author: JI Xiangdong, jxdsn@163.com
Received Date: 3 June 2020
Revised Date: 7 July 2020
Accepted Date: 6 August 2020

Fund Project: the Gansu Provincial Science and Technology Program Funded Project 18JR3RG205the National Natural Science Foundation of China 21761011the Scientific Research Foundation of the Higher Education Institutions of Gansu Province 2018A-088Supported by the National Natural Science Foundation of China(No.21761011), the Gansu Provincial Science and Technology Program Funded Project(No.18JR3RG205) and the Scientific Research Foundation of the Higher Education Institutions of Gansu Province(No.2018A-088)

Figures(11)

A new long-chain alkoxyphenylhydrozone derivative, 1-(2, 4-dinitrophenyl)-2-(4-(tetradecyloxy) benzylidene) hydrazine, was designed and synthesized. The ultraviolet-visible (UV-Vis) spectra and naked-eye recognition property of the receptor R for nine kinds of anions (F^-, Cl^-, Br^-, I^-, HSO₄^-, NO₃^-, ClO₄^-, H₂PO₄^-, Ac^-) were studied. The results indicate that the receptor R shows high UV-Vis and naked-eye recognition property towards F^-, Ac^- and H₂PO₄^- in dimethylsulfoxide (DMSO) solution. Single colorimetric recognition of F^- is found by UV-Vis analysis and naked-eye recognition in H₂O/DMSO (1/9) solution, and the LOD (limit of detection) of receptor R for F^- is 7.02×10^-7 mol/L. The naked recognition paper of receptor R is prepared, and the Job's plot indicates the formation of complex between receptor R and F^- is in 1:1 stoichiometric ratios. The recognition mechanism of receptor R is the "hydrogen-bond" recognition.
- Schiff base receptor,
- ion detection,
- chemosensor for floride ion,
- naked-eye detection,
- anions
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