Citation: CHENG Yinjie, ZHANG Lu, HU Renjie, WANG Ying, JIN Xuexin, QIU Shuo, ZHANG Haoyan, JIANG Dawei. Preparation and Characterization of Hydrogen-Bonded Carbon Nanotubes Reinforced Self-healing Composites[J]. Chinese Journal of Applied Chemistry, ;2020, 37(10): 1147-1155. doi: 10.11944/j.issn.1000-0518.2020.10.200112 shu

Preparation and Characterization of Hydrogen-Bonded Carbon Nanotubes Reinforced Self-healing Composites

Heilongjiang Key Laboratory of Molecular Design and Preparation of Flame Retardant Materials, Chemical Engineering and Resource Utilization, Northeast Forestry University, Harbin 150040, China

Corresponding author: JIANG Dawei, sharkwei12345@163.com
Received Date: 19 April 2020
Revised Date: 22 June 2020
Accepted Date: 20 July 2020

Fund Project: the Fundamental Research Funds for the Central Universities 2572018BC27the Project of Heilongjiang Provincial Youth Science Foundation QC2017038Heilongjiang Provincial Government Postdoctoral Grants LBH-Z16004Heilongjiang Province Postdoctoral Special Funding LBH-TZ13China Postdoctoral Science Foundation Grant 2016M601402Supported by the Fundamental Research Funds for the Central Universities(No.2572018BC27), the Project of Heilongjiang Provincial Youth Science Foundation(No.QC2017038), Heilongjiang Province Postdoctoral Special Funding(No.LBH-TZ13), Heilongjiang Provincial Government Postdoctoral Grants(No.LBH-Z16004) and China Postdoctoral Science Foundation Grant(No.2016M601402)

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The hydrogen-bonded self-healing composites were manufactured successfully (dimer acid, diethylenetriamine, and urea as raw materials, and carbon nanotubes as reinforcing agents). The composites have good mechanical properties and can self-heal at room-temperature (30 ℃). The mechanism of self-healing was proposed in the paper. The stress-strain tests were performed on self-healing composites with different amounts of carbon nanotubes. It is found that the stress and the strain of the composites increases with the increased addition of carbon nanotubes. The stress of composites can reach 4 MPa and the strain increases more than 6% as 9% (mass fraction) of carbon nanotubes is added into the composites. The surface morphology, self-repairing performance and thermal stability of the self-healing composites with 9% (mass fraction) of carbon nanotubes were tested. The results show that carbon nanotubes have good compatibility with the material, and the morphologies of the surface and fracture surface of the cut composites are similar. The self-healing efficiency of composites can reach 100% at room temperature for 24 h. The self-healing efficiency is more than 90% after 10 fracture-healing cycles. The composites have excellent thermal stability, and the temperature at the maximum mass loss rate is 474 ℃. The composites provide an option for next-generation skin sensors and wearable smart devices.
- self-healing polymer,
- carbon nanotubes,
- hydrogen bonds
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