Citation: FU Fengyan, CHENG Jingquan, ZHANG Jie, GAO Zhihua. Recent Development in Ionic Exchange Groups-Based Anion Exchange Membrane[J]. Chinese Journal of Applied Chemistry, ;2020, 37(10): 1112-1126. doi: 10.11944/j.issn.1000-0518.2020.10.200095 shu

Recent Development in Ionic Exchange Groups-Based Anion Exchange Membrane

Department of Applicative Chemistry, Hengshui University, Hengshui, Hebei 053000, China

Corresponding author: FU Fengyan, 1374195561@qq.com
Received Date: 1 April 2020
Revised Date: 13 May 2020
Accepted Date: 4 June 2020

Fund Project: Colleges and Universities in Hebei Province Science Research Fund BJ2019206Supported by the Colleges and Universities in Hebei Province Science Research Fund(No.BJ2019206), and the Hengshui University High-level Talents Research Start-up Fund

Figures(9)

Anion exchange membrane fuel cells (AEMFCs) have attracted worldwide attention. To achieve high performance in AEMFCs, anion exchange membranes (AEMs) should own high ion conductivity and good alkaline stability. AEMs contain cationic groups and polymer backbone, while ionic groups play very important role in determining the overall stability and conductivity for the AEMs apart from polymer backbones. In this paper, the structure, alkaline stability and ion conductivity of AEMs with different kinds of cationic groups such as quaternary ammonium, guanidinium, imidazolium, phosphonium, metal cation, N-spirocyclic cations, piperidinium and pyrrolidinium are introduced in detail, and the development trend of the cationic groups are also discussed.
- anion exchange membrane,
- ionic exchange group,
- alkaline stability,
- ionic conductivity
1. [1]
  Merle G, Wessling M, Nijmeijer K. Anion Exchange Membranes for Alkaline Fuel Cells:A Review[J]. J Membr Sci, 2011,377(1/2):1-35.
2. [2]
  Matsumoto K, Fujigaya T, Yanagi H. Very High Performance Alkali Anion Exchange Membrane Fuel Cell[J]. Adv Funct Mater, 2011,21(6):1089-1094. doi: 10.1002/adfm.201001806
3. [3]
  Kruusenberg I, Matisen L, Shah Q. Non-platinum Cathode Catalysts for Alkaline Membrane Fuel Cell[J]. Int J Hydrogen Energy, 2012,37(5):4406-4412. doi: 10.1016/j.ijhydene.2011.11.143
4. [4]
  Maurya S, Shin S H, Kim Y. A Review on Recent Developments of Anion Exchange Membranes for Fuel Cells and Redox Flow Batteries[J]. RSC Adv, 2015,5(47):37206-37230. doi: 10.1039/C5RA04741B
5. [5]
  Dekel D R. Review of Cell Performance in Anion Exchange Membrane Fuel Cells[J]. J Power Sources, 2018,375:158-169. doi: 10.1016/j.jpowsour.2017.07.117
6. [6]
  Meek K M, Nykaza J R, Elabd Y A. Alkaline Chemical Stability and Ion Transport in Polymerized Ionic Liquids with Various Backbones and Cations[J]. Macromolecules, 2016,49(9):3382-3394. doi: 10.1021/acs.macromol.6b00434
7. [7]
  Cheng J, Yang G, Zhang K. Guanidimidazole Quanternized and Cross-linked Alkaline Polymer Electrolyte Membrane for Fuel Cell Application[J]. J Membr Sci, 2016,501:100-108. doi: 10.1016/j.memsci.2015.12.012
8. [8]
  Gong X, Yan X, Li T. Design of Pendent Imidazolium Side Chain with Flexible Ether Containing Spacer for Alkaline Anion Exchange Membrane[J]. J Membr Sci, 2017,523:216-224. doi: 10.1016/j.memsci.2016.09.050
9. [9]
  Zhang B, Kaspar R B, Gu S. A New Alkali Stable Phosphonium Cation Based on Fundamental Understangding of Degradation Mechanisms[J]. ChemSusChem, 2016,9(17):2374-2379. doi: 10.1002/cssc.201600468
10. [10]
  Zha Y P, Disabb-Miller M L, Johnson Z D. Metal-Cation-Based Anion Exchange Membranes[J]. J Am Chem Soc, 2012,134(10):4493-4496. doi: 10.1021/ja211365r
11. [11]
  Wei Y, Kevin J T N, Geoffrey W C. Alkaline-Stable Anion Exchange Membranes:A Review of Synthetic Approaches[J]. Prog Polym Sci, 2020,100101177. doi: 10.1016/j.progpolymsci.2019.101177
12. [12]
  Dong X, Hou S, Mao H. Novel Hydrophilic-Hydrophobic Block Copolymer Based on Cardo Poly(arylene ether sulfone)s with Bis-Quaternary Ammonium Moieties for Anion Exchange Membranes[J]. J Membr Sci, 2016,518:31-39. doi: 10.1016/j.memsci.2016.06.036
13. [13]
  Sun Z, Pan J, Guo J. The Alkaline Stability of Anion Exchange Membrane for Fuel Cell Applications:The Effects of Alkaline Media[J]. Adv Sci, 2018,5(8)1800065. doi: 10.1002/advs.201800065
14. [14]
  Edson J, Macomber C, Pivovar B. Hydroxide Based Decomposition Pathways of Alkyltrimethylammonium Cations[J]. J Membr Sci, 2012,399:49-59.
15. [15]
  Li N, Leng Y, Hickner M A. Highly Stable, Anion Conductive, Comb-Shaped Copolymers for Alkaline Fuel Cells[J]. J Am Chem Soc, 2013,135(27):10124-10133. doi: 10.1021/ja403671u
16. [16]
  Zhu L, Pan J, Christensen C M. Functionalization of Poly(2, 6-dimethyl-1, 4-phenylene oxide)s with Hindered Fluorene Side Chains for Anion Exchange Membranes[J]. Macromolecules, 2016,49(9):3300-3309. doi: 10.1021/acs.macromol.6b00578
17. [17]
  Dang H S, Jannasch P. Exploring Different Cationic Alkyl Side Chain Designs for Enhanced Alkaline Stability and Hydroxide Ion Conductivity of Anion-Exchange Membranes[J]. Macromolecules, 2015,48(16):5742-5751. doi: 10.1021/acs.macromol.5b01302
18. [18]
  Zhang M, Shan C R, Liu L. Facilitating Anion Transport in Polyolefin-Based Anion Exchange Membranes via Bulky Side Chains[J]. ACS Appl Mater Interfaces, 2016,8(35):23321-23330. doi: 10.1021/acsami.6b06426
19. [19]
  Jeon J Y, Park S, Han J. Synthesis of Aromatic Anion Exchange Membranes by Friedel-Crafts Bromoalkylation and Cross-linking of Polystyrene Block Copolymers[J]. Macromolecules, 2019,52(5):2139-2147. doi: 10.1021/acs.macromol.8b02355
20. [20]
  Lin B C, Xu F, Su Y. Facile Preparation of Anion-Exchange Membrane Based on Polystyrene-b-Polybutadiene-b-Polystyrene for the Application of Alkaline Fuel Cells[J]. Ind Eng Chem Res, 2019,58(49):22299-22305. doi: 10.1021/acs.iecr.9b05314
21. [21]
  Peng J W, Liang M H, Liu Z C. Poly(arylene ether sulfone) Crosslinked Networks with Pillar[5] arene Units Grafted by Multiple Long-Chain Quaternary Ammonium Salts for Anion Exchange Membranes[J]. Chem Commun, 2020,56(6):928-931. doi: 10.1039/C9CC07105A
22. [22]
  Fu F Y, Xu H L, Dong Y. Design of Polyphosphazene-Based Graft Copolystyrenes with Alkylsulfonate Branch Chains for Proton Exchange Membranes[J]. J Membr Sci, 2015,489:119-128. doi: 10.1016/j.memsci.2015.04.016
23. [23]
  Fu F Y, Xu H L, Dong Y. Polyphosphazene-based Copolymers Containing Pendant Alkylsulfonic Acid Groups as Proton Exchange Membranes[J]. Solid State Ionics, 2015,278:58-64. doi: 10.1016/j.ssi.2015.05.018
24. [24]
  GAO Li, WU Xuemei, YAN Xiaoming. Alkali Stability of Anion Exchange Membrane[J]. Chinese Sci Bull, 2019,64:145-152.
25. [25]
  XUE Boxin, ZHENG Jifu, ZHANG Suobo. Advances in Alkaline Stable Guanidinium Based Anion Exchange Membranes[J]. Chinese Sci Bull, 2019,64:134-144.
26. [26]
  Wang J, Li S, Zhang S. Novel Hydroxide-Conducting Polyelectrolyte Composed of an Poly(arylene ether sulfone) Containing Pendant Quaternary Guanidinium Groups for Alkaline Fuel Cell Applications[J]. Macromolecules, 2010,43(8):3890-3896.
27. [27]
  Lin X, Wu L, Liu Y. Alkali Resistant and Conductive Guanidinium-Based Anion-Exchange Membranes for Alkaline Polymer Electrolyte Fuel Cells[J]. J Power Sources, 2012,217:373-380. doi: 10.1016/j.jpowsour.2012.05.062
28. [28]
  Qu C, Zhang H, Zhang F. A High-Performance Anion Exchange Membrane Based on Bi-Guanidinium Bridged Polysilsesquioxane for Alkaline Fuel Cell Application[J]. J Mater Chem, 2012,22(17):8203-8207. doi: 10.1039/c2jm16211c
29. [29]
  Sajjada S, Hong Y, Liu F. Synthesis of Guanidinium-Based Anion Exchange Membranes and Their Stability Assessment[J]. Polym Adv Technol, 2014,25(1):108-116.
30. [30]
  Kim D, Fujimoto C, Hibbs M. Resonance Stabilized Perfluorinated Ionomers for Alkaline Membrane Fuel Cells[J]. Macromolecules, 2013,46(19):7826-7833. doi: 10.1021/ma401568f
31. [31]
  Cheng J, Yang G, Zhang K. Guanidimidazole-Quanternized and Cross-linked Alkaline Polymer Electrolyte Membrane for Fuel Cell Application[J]. J Membr Sci, 2016,501:100-108. doi: 10.1016/j.memsci.2015.12.012
32. [32]
  Xue B, Dong X, Li Y. Synthesis of Novel Guanidinium-Based Anion-Exchange Membranes with Controlled Microblock Structures[J]. J Membr Sci, 2017,537:151-159. doi: 10.1016/j.memsci.2017.05.030
33. [33]
  Xue B X, Wang F, Zheng J F. Highly Stable Polysulfone Anion Exchange Membranes Incorporated with Bulky Alkyl Substituted Guanidinium Cations[J]. Mol Syst Des Eng, 2019,4(5):1039-1047. doi: 10.1039/C9ME00064J
34. [34]
  Xue B X, Wang Q, Zheng J F. Bi-guanidinium-Based Crosslinked Anion Exchange Membranes:Synthesis, Characterization, and Properties[J]. J Membr Sci, 2020,601117923. doi: 10.1016/j.memsci.2020.117923
35. [35]
  Zhuo Y Z, Lai A L, Zhang Q G. Enhancement of Hydroxide Conductivity by Grafting Flexible Pendant Imidazolium Groups into Poly(arylene ether sulfone) as Anion Exchange Membranes[J]. J Mater Chem A, 2015,3(35):18105-18114. doi: 10.1039/C5TA04257G
36. [36]
  Lee B, Yun D Y, Lee S. Development of Highly Alkaline Stable OH^--Conductors Based on Imidazolium Cations with Various Substituents for Anion Exchange Membrane-Based Alkaline Fuel Cells[J]. J Phys Chem C, 2019,123(22):13508-13518. doi: 10.1021/acs.jpcc.9b02991
37. [37]
  Guo D, Lai A N, Lin C X. Imidazolium-Functionalized Poly(arylene ether sulfone) Anion-Exchange Membranes Densely Grafted with Flexible Side Chains for Fuel Cells[J]. ACS Appl Mater Interfaces, 2016,8(38):25279-25288. doi: 10.1021/acsami.6b07711
38. [38]
  Holl czki O, Terleczky P, Szieberth D. Hydrolysis of Imidazole-2-ylidenes[J]. J Am Chem Soc, 2011,133(4):780-789. doi: 10.1021/ja103578y
39. [39]
  Lin B C, Dong H L, Li Y Y. Alkaline Stable C2-Substituted Imidazolium-Based Anion-Exchange Membranes[J]. Chem Mater, 2013,25(9):1858-1867. doi: 10.1021/cm400468u
40. [40]
  Price S C, Williams K S, Beyer F L. Relationships Between Structure and Alkaline Stability of Imidazolium Cations for Fuel Cell Membrane Applications[J]. ACS Macro Lett, 2014,3(2):160-165. doi: 10.1021/mz4005452
41. [41]
  Hugar K M, Kostalik H A, Coates G W. Imidazolium Cations with Exceptional Alkaline Stability:A Systematic Study of Structure-Stability Relationships[J]. J Am Chem Soc, 2015,137(27):8730-8737. doi: 10.1021/jacs.5b02879
42. [42]
  Gu F L, Dong H L, Li Y Y. Highly Stable N3-Substituted Imidazolium-Based Alkaline Anion Exchange Membranes:Experimental Studies and Theoretical Calculations[J]. Macromolecules, 2014,47(1):208-216. doi: 10.1021/ma402334t
43. [43]
  Zhu Y, He Y B, Ge X L. Benzyltetramethylimidazolium-Based Membrane with Exceptional Alkaline Stability in Fuel Cell:Role of Structure in Alkaline Stability[J]. J Mater Chem A, 2018,6:527-534. doi: 10.1039/C7TA09095A
44. [44]
  Wang J, Gu S, Kaspar R B. Stabilizing the Imidazolium Cation in Hydroxide-Exchange Membranes for Fuel Cells[J]. ChemSusChem, 2013,6(11):2079-2082. doi: 10.1002/cssc.201300285
45. [45]
  Thomas O D, Soo K J W Y, Peckham T J P. Anion Conducting Poly(dialkyl benzimidazolium) Salts[J]. Polym Chem, 2011,2(8):1641-1643. doi: 10.1039/c1py00142f
46. [46]
  Wright A G, Weissbach T, Holdcroft S. Poly(phenylene) and M-terphenyl as Powerful Protecting Groups for the Preparation of Stable Organic Hydroxides[J]. Angew Chem Int Ed, 2016,55(15):4818-4821. doi: 10.1002/anie.201511184
47. [47]
  Lin B C, Xu F, Su Y. Ether-free Polybenzimidazole Bearing Pendant Imidazolium Groups for Alkaline Anion Exchange Membrane Fuel Cells Application[J]. ACS Appl Energy Mater, 2020,3(1):1089-1098. doi: 10.1021/acsaem.9b02123
48. [48]
  Ye Y S, Stokes K K, Beyer F L. Development of Phosphonium-Based Bicarbonate Anion Exchange Polymer Membranes[J]. J Membr Sci, 2013,443:93-99. doi: 10.1016/j.memsci.2013.04.053
49. [49]
  Noonan K J T, Hugar K M, Kostalik H A. Phosphonium-Functionalized Polyethylene:A New Class of Base-Stable Alkaline Anion Exchange Membranes[J]. J Am Chem Soc, 2012,134(44):18161-18164. doi: 10.1021/ja307466s
50. [50]
  Womble C T, Coates G W, Matyjaszewski K. Tetrakis(dialkylamino)phosphonium Polyelectrolytes Prepared by Reversible Addition-Fragmentation Chain Transfer Polymerization[J]. ACS Macro Lett, 2016,5(2):253-257. doi: 10.1021/acsmacrolett.5b00910
51. [51]
  Cotanda P, Sudre G, Modestino M A. High Anion Conductivity and Low Water Uptake of Phosphonium Containing Diblock Copolymer Membranes[J]. Macromolecules, 2014,47(21):7540-7547. doi: 10.1021/ma501744w
52. [52]
  Zhang B Z, Long H, Kaspar R B. Relating Alkaline Stability to the Structure of Quaternary Phosphonium Cations[J]. RSC Adv, 2018,8(47):26640-26645. doi: 10.1039/C8RA03440K
53. [53]
  Wan W, Yang X Y, Smith R C. Convenient Route to Tetraarylphosphonium Polyelectrolytes via Metal-Catalysed P-C Coupling Polymerisation of Aryl Dihalides and Diphenylphosphine[J]. Chem Commun, 2017,53(1):252-254. doi: 10.1039/C6CC08938K
54. [54]
  Han H S, Ma H M, Yu J H. Preparation and Performance of Novel Tetraphenylphosphonium-Functionalized Polyphosphazene Membranes for Alkaline Fuel Cells[J]. Eur Polym J, 2019,114:109-117. doi: 10.1016/j.eurpolymj.2019.02.022
55. [55]
  Liu Y, Zhang B, Kinsinger C. Anion Exchange Membranes Composed of a Poly(2, 6-dimethyl-1, 4-phenylene oxide) Random Copolymer Functionalized with a Bulky Phosphonium Cation[J]. J Membr Sci, 2016,506:50-59. doi: 10.1016/j.memsci.2016.01.042
56. [56]
  Barnes U M, Du Y F, Zhang W X. Phosphonium-Containing Block Copolymer Anion Exchange Membranes:Effect of Quaternization Level on Bulk and Surface Morphologies at Hydrated and Dehydrated States[J]. Macromolecules, 2019,52(16):6097-6106. doi: 10.1021/acs.macromol.9b00665
57. [57]
  Ran J, Wu L, He Y B. Ion Exchange Membranes:New Developments and Applications[J]. J Membr Sci, 2017,522:267-291. doi: 10.1016/j.memsci.2016.09.033
58. [58]
  Zha Y, Disabb-Miller M L, Johnson Z D. Metal-Cation-Based Anion Exchange Membranes[J]. J Am Chem Soc, 2012,134(10)44934496.
59. [59]
  Disabb-Miller M L, Zha Y P, DeCarlo A J. Water Uptake and Ion Mobility in Cross-Linked Bis(terpyridine)ruthenium-Based Anion Exchange Membranes[J]. Macromolecules, 2013,46(23):9279-9287. doi: 10.1021/ma401701n
60. [60]
  Kwasny M T, Tew G N. Expanding Metal Cation Options in Polymeric Anion Exchange Membranes[J]. J Mater Chem A, 2017,5(4):1400-1405. doi: 10.1039/C6TA07990C
61. [61]
  Zhu T, Xu S, Rahman A. Cationic Metallo-Polyelectrolytes for Robust Alkaline Anion-Exchange Membranes[J]. Angew Chem Int Ed, 2018,57:2388-2392. doi: 10.1002/anie.201712387
62. [62]
  Zhu T Y, Sha Y, Firouzjaie H A. Rational Synthesis of Metallo-Cations Toward Redox-and Alkaline-Stable Metallo-Polyelectrolytes[J]. J Am Chem Soc, 2020,142(2):1083-1089. doi: 10.1021/jacs.9b12051
63. [63]
  Gu S, Wang J, Kaspar R B. Permethyl Cobaltocenium (Cp^*2Co⁺) as an Ultra-stable Cation for Polymer Hydroxide-Exchange Membranes[J]. Sci Rep, 2015,511668. doi: 10.1038/srep11668
64. [64]
  Wu B, Ge L, Yu D. Cationic Metal-Organic Framework Porous Membranes with High Hydroxide Conductivity and Alkaline Resistance for Fuel Cells[J]. J Mater Chem A, 2016,4(38):14545-14549. doi: 10.1039/C6TA06661E
65. [65]
  Olsson J S, Pham T H, Jannasch P. Poly(arylene piperidinium) Hydroxide Ion Exchange Membranes:Synthesis, Alkaline stability, and Conductivity[J]. Adv Funct Mater, 2017,28(2)1702758.
66. [66]
  Döbbelin M, Azcune I, Bedu M. Synthesis of Pyrrolidinium-Based Poly(ionic liquid) Electrolytes with Poly(ethylene glycol) Side Chains[J]. Chem Mater, 2012,24(9):1583-1590. doi: 10.1021/cm203790z
67. [67]
  Pham T H, Olsson J S, Jannasch P. N-Spirocyclic Quaternary Ammonium Ionenes for Anion-Exchange Membranes[J]. J Am Chem Soc, 2017,139(8):2888-2891. doi: 10.1021/jacs.6b12944
68. [68]
  Olsson J S, Pham T H, Jannasch P. Poly(N, N-diallylazacycloalkane)s for Anion-Exchange Membranes Functionalized with N-Spirocyclic Quaternary Ammonium Cations[J]. Macromolecules, 2017,50(7):2784-2793. doi: 10.1021/acs.macromol.7b00168
69. [69]
  Pham T H, Olsson J S, Jannasch P. Poly(arylene alkylene)s with Pendant N-Spirocyclic Quaternary Ammonium Cations for Anion Exchange Membranes[J]. J Mater Chem A, 2018,6(34):16537-16547. doi: 10.1039/C8TA04699A
70. [70]
  Chen N J, Long C, Li Y X. Ultrastable and High Ion-Conducting Polyelectrolyte Based on Six-Membered N-Spirocyclic Ammonium for Hydroxide Exchange Membrane Fuel Cell Applications[J]. ACS Appl Mater Interfaces, 2018,10(18):15720-15732. doi: 10.1021/acsami.8b02884
71. [71]
  Chen N J, Lu C R, Li Y X. Robust Poly(aryl piperidinium)/N-Spirocyclic Poly(2, 6-dimethyl-1, 4-phenyl) for Hydroxide-Exchange Membranes[J]. J Membr Sci, 2019,572:246-254. doi: 10.1016/j.memsci.2018.10.067
72. [72]
  Chu X M, Liu L, Huang Y D. Practical Implementation of Bis-six-membered N-Cyclic Quaternary Ammonium Cations in Advanced Anion Exchange Membranes for Fuel Cells:Synthesis and Durability[J]. J Membr Sci, 2019,578:239-250. doi: 10.1016/j.memsci.2019.02.051
73. [73]
  Zhang Y, Chen W T, Yan X M. Ether Spaced N-Spirocyclic Quaternary Ammonium Functionalized Crosslinked Polysulfone for High Alkaline Stable Anion Exchange Membranes[J]. J Membr Sci, 2020,598117650. doi: 10.1016/j.memsci.2019.117650
74. [74]
  Lin C X, Yu D M, Wang J X. Facile Construction of Poly(arylene ether)s-Based Anion Exchange Membranes Bearing Pendent N-Spirocyclic Quaternary Ammonium for Fuel Cells[J]. Int J Hydrogen Energy, 2019,44(48):26565-26576. doi: 10.1016/j.ijhydene.2019.08.092
75. [75]
  Gu F L, Dong H L, Li Y Y. Base Stable Pyrrolidinium Cations for Alkaline Anion Exchange Membrane Applications[J]. Macromolecules, 2014,47(19):6740-6747. doi: 10.1021/ma5015148
76. [76]
  Dong X, Lv D, Zheng J F. Pyrrolidinium-Functionalized Poly(arylene ether sulfone)s for Anion Exchange Membranes:Using Densely Doncentrated Ionic Groups and Block Design to Improve Membrane Performance[J]. J Membr Sci, 2017,535:301-311. doi: 10.1016/j.memsci.2017.04.054
77. [77]
  Fujimoto C, Kim D S, Hibbs M. Backbone Stability of Quaternized Polyaromatics for Alkaline Membrane Fuel Cells[J]. J Membr Sci, 2012,423438449.
78. [78]
  Lee W H, Mohanty A D, Bae C. Fluorene-Based hydroxide Ion Conducting Polymers for Chemically Stable Anion Exchange Membrane Fuel Cells[J]. ACS Macro Lett, 2015,4(4)453457.
79. [79]
  Lee W H, Kim Y S, Bae C. Robust Hydroxide Ion Conducting Poly(biphenyl alkylene)s for Alkaline Fuel Cell Membranes[J]. ACS Macro Lett, 2015,4(8):814-818. doi: 10.1021/acsmacrolett.5b00375
80. [80]
  Olsson J S, Pham T H, Jannasch P. Poly(arylene piperidinium) Hydroxide Ion Exchange Membranes:Synthesis, Alkaline Stability, and Conductivity[J]. Adv Funct Mater, 2017,28(2)1702758.
81. [81]
  Wang J H, Zhao Y, Brian P. Poly(aryl piperidinium) Membranes and Ionomers for Hydroxide Exchange Membrane Fuel Cells[J]. Nat Energy, 2019,4(5):392-398. doi: 10.1038/s41560-019-0372-8
82. [82]
  Chu X M, Shi Y, Liu L. Piperidinium-Functionalized Anion Exchange Membranes and Their Application in Alkaline Fuel Cells and Water Electrolysis[J]. J Mater Chem A, 2019,7(13):7717-7727. doi: 10.1039/C9TA01167F
83. [83]
  Wang F, Xue B X, Zhou S Y. Synthesis and Property of Novel Anion Exchange Membrane Based on Poly(aryl ether sulfone)s Bearing Piperidinium Moieties[J]. J Membr Sci, 2019,591117334. doi: 10.1016/j.memsci.2019.117334
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14. [14]
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15. [15]
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16. [16]
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17. [17]
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18. [18]
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19. [19]
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20. [20]
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沈阳化工大学材料科学与工程学院沈阳 110142