Citation: ZHANG Xinyu, QU Jiangying, TANG Zhanlei, LI Jielan, WANG Tao, GAO Feng. In Situ Synthesis of Nitrogen-Doped Carbon Coated Co_xP Composites and Their Lithium Properties[J]. Chinese Journal of Applied Chemistry, ;2020, 37(10): 1172-1180. doi: 10.11944/j.issn.1000-0518.2020.10.200072 shu

In Situ Synthesis of Nitrogen-Doped Carbon Coated Co_xP Composites and Their Lithium Properties

ZHANG Xinyu ^a ,
QU Jiangying ^b ,
TANG Zhanlei ^c ,
LI Jielan ^a ,
WANG Tao ^b ,
GAO Feng ^b,,

a.
Faculty of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian, Liaoning 116029, China
b.
School of Environment and Civil Engineering, Dongguan University of Technology, Dongguan, Guangdong 523808, China
c.
Guangdong Kaijin New Energy Technology Corp, Ltd. Dongguan, Guangdong 523808, China

Corresponding author: GAO Feng, fenggao2003@163.com
Received Date: 16 March 2020
Revised Date: 21 April 2020
Accepted Date: 18 May 2020

Fund Project: the NSFC 51972059the NSFC U1610114the CSC Fund 201908440038Supported by the NSFC(No.U1610114, No.51972059), and the CSC Fund(No.201908440038)

Figures(5)

Nitrogen-doped carbon coated Co₂P@N-C and CoP@N-C composites were in situ synthesized at 800 ℃ using zeolitic imidazolate framework-67 (ZIF-67) as cobalt/nitrogen/carbon precursor and red phosphorus as phosphorus source, and their electrochemical properties were studied as anode materials of lithium ion batteries. It is found that the resulted products can be tailored by the ratio of ZIF-67 to red phosphorus. The obtained Co₂P@N-C and CoP@N-C composites show regular dodecahedron and the size of about 250 to 400 nm and exhibit good conductivity. When they are used as anode materials, the first discharge capacity of the Co₂P@N-C and CoP@N-C composites are 942 and 1170.6 mA·h/g at the current density of 0.05 A/g, respectively. Even at the current density of 1 A/g, their capacities are maintained at 306.6 and 180.3 mA·h/g after 500 cycles, respectively. We have provided a green and easy method for the synthesis of Co_xP@C composites for lithium ion battery.
- lithium ion batteries,
- cathode material,
- Co_xP composites,
- zeolitic imidazolate framework-67,
- red phosphorus,
- in situ nitrogen doped carbon
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In Situ Synthesis of Nitrogen-Doped Carbon Coated CoxP Composites and Their Lithium Properties

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通讯作者: 陈斌, bchen63@163.com

In Situ Synthesis of Nitrogen-Doped Carbon Coated Co_xP Composites and Their Lithium Properties