Citation: CHANG Fengxia, SHANG Zongyi, DONG Qing, LONG Zhiyan, DENG Yixue. Simultaneous Determination of Catechol and Hydroquinone by Copper Oxide Nanoparticles and Carbon Nanotubes Modified Glassy Carbon Electrode[J]. Chinese Journal of Applied Chemistry, ;2020, 37(10): 1195-1202. doi: 10.11944/j.issn.1000-0518.2020.10.200048 shu

Simultaneous Determination of Catechol and Hydroquinone by Copper Oxide Nanoparticles and Carbon Nanotubes Modified Glassy Carbon Electrode

College of Chemistry and Environmental Protection Engineering, Southwest Minzu University, Chengdu 610041, China

Corresponding author: CHANG Fengxia, changfengxia@swun.edu.cn
Received Date: 21 February 2020
Revised Date: 18 March 2020
Accepted Date: 9 May 2020

Fund Project: Southwest Minzu University Fundamental Research Funds for the Central Universities 2020NQN07Supported by Southwest Minzu University Fundamental Research Funds for the Central Universities(No.2020NQN07)

Figures(6)

Copper oxide nanoparticles and carboxylated multi-walled carbon nanotubes were used as modification materials for glassy carbon electrodes in this study. This nanocomposite combined the advantages of electrochemical signal amplification and electrocatalysis, and the as-prepared modified electrode could separate the redox peaks of catechol and hydroquinone and enlarge the peak currents further. Thus, this electrochemical sensor based on copper oxide nanoparticles and carbon nanotubes can be used for the simultaneous determination of catechol and hydroquinone. The ratio of copper oxide nanoparticles and carbon nanotubes in the nanocomposite, the cast volume and pH of the electrolyte are optimized via cyclic voltammetry. The optimal mass ratio between copper oxide nanoparticles and carbon nanotubes is 5:1. The optimal cast volume is 9 μL and phosphate buffer solution with pH=7.4 is used as the electrolyte. At the optimized conditions, the peak currents obtained with differential pulse voltammetric determination show good linear relationships with concentrations of catechol and hydroquinone in the range from 6.0×10^-7~3.0×10^-3 mol/L with detection limits of 1.0×10^-7 mol/L and 1.60×10^-7 mol/L (S/N=3), resepectively. This method is cheap, easy to operate and fast, and the recovery rates of practical water samples using this method are in a satisfactory range (94.6%~101.1%). Therefore, this proposed method has a good prospect of practical application.
- copper oxide nanoparticles,
- carbon nanotubes,
- catechol,
- hydroquinone,
- simultaneous detection
1. [1]
  Wang H F, Wu Y Y, Yan X P. Room-Temperature Phosphorescent Discrimination of Catechol from Resorcinol and Hydroquinone Based on Sodium Tripolyphosphate Capped Mn-Doped ZnS Quantum Dots[J]. Anal Chem, 2013,85(3):1920-1925.
2. [2]
  Chen T T, Xu J Q, Arsalan M. Controlled Synthesis of Au@Pd Core-Shell Nanocomposites and their Application for Electrochemical Sensing of Hydroquinone[J]. Talanta, 2019,198:78-85.
3. [3]
  Huang D L, Wang J, Cheng F. Synergistic Effect of a Cobalt Fluoroporphyrin and Graphene Oxide on the Simultaneous Voltammetric Determination of Catechol and Hydroquinone[J]. Microchim Acta, 2019,186(6):1-11.
4. [4]
  Marrubini G, Calleri E, Coccini T. Direct Analysis of Phenol, Catechol and Hydroquinone in Human Urine by Coupled-Column HPLC with Fluorimetric Detection[J]. Chromatographia, 2005,62(1/2):25-31.
5. [5]
  Xie T Y, Liu Q W, Shi Y R. Simultaneous Determination of Positional Isomers of Benzenediols by Capillary Zone Electrophoresis with Square Wave Amperometric detection[J]. J Chromatogr A, 2006,1109(2):317-321.
6. [6]
  Liu J, Lin Z. Simultaneous Determination of Mixed Phenol, Catechol, and Quinol by Double Fourier Transform Filtering and Second Ratio Spectra Derivative Spectrophotometry[J]. Spectrosc Spectr Anal, 2000,20(4):480-483.
7. [7]
  Cui H, Zhang Q L, Myint A. Chemiluminescence of Cerium(IV)-Rhodamine 6G-Phenolic Compound System[J]. J Photochem Photobiol A, 2006,181(2/3):238-245.
8. [8]
  Chen T W, Yu X N, Li S J. Simultaneous Determination of Dihydroxybenzene Isomers Using Glass Carbon Electrode Modified with 3D CNT-Graphene Decorated with Au Nanoparticles[J]. Int J Electrochem Sc, 2019,14(8):7037-7046.
9. [9]
  Yang S Y, Yang M, Liu Q Y. An Ultrasensitive Electrochemical Sensor Based on Multiwalled Carbon Nanotube@Reduced Graphene Oxide Nanoribbon Composite for Simultaneous Determination of Hydroquinone, Catechol and Resorcinol[J]. J Electrochem Soc, 2019,166(6):B547-B553.
10. [10]
  Zhao C, Song J F, Zhang J C. Determination of Total Phenols in Environmental Wastewater by Flow-Injection Analysis with a Biamperometric Detector[J]. Anal Bioanal Chem, 2002,374(3):498-504.
11. [11]
  WANG Zhongteng, LIU Hanhan, TENG Hui. A Voltammetric Sensor Based on Graphene-Gold Nanocomposite Film for Simultaneous Determination of Hydroquinone and Catechol[J]. J Anhui Sci Tech Univ, 2018,32(5):64-72.
12. [12]
  FU Ju, TAN Xiaohong, SONG Xinjian. Polypyrimidine/Graphene Composite Film Modified Electrode for the Simultaneous Detection of Catechol and Hydroquinone[J]. J Hubei Univ Nationnalities(Nat Sci Edn), 2016,34(2):195-198.
13. [13]
  Zhao L, Yu J, Yue S Z. Nickel Oxide/Carbon Nanotube Nanocomposites Prepared by Atomic Layer Deposition for Electrochemical Sensing of Hydroquinone and Catechol[J]. J Electroanal Chem, 2018,808:245-251.
14. [14]
  Alshahrani L A, Miao L Q, Zhang Y Y. 3D-Flower-Like Copper Sulfide Nanoflake-Decorated Carbon Nanofragments-Modified Glassy Carbon Electrodes for Simultaneous Electrocatalytic Sensing of Coexisting Hydroquinone and Catechol[J]. Sensors, 2019,19(10):1-12.
15. [15]
  Bozkurt G, Bayrakceken A, Ozer A K. Synthesis and Characterization of CuO at Nanoscale[J]. Appl Surf Sci, 2014,318:244-250.
16. [16]
  Khanna P K, Gaikwad S, Adhyapak R. Synthesis and Characterization of Copper Nanoparticles[J]. Mater Lett, 2007,61(25):4711-4714.
17. [17]
  Teng F, Yao W Q, Zheng Y F. Synthesis of Flower-like CuO Nanostructures as a Sensitive Sensor for Catalysis[J]. Sens Actuators B, 2008,134(2):761-768.
18. [18]
  Patil S A, Patil L A, Patil D R. CuO-Modified Tin Titanate Thick Film Resistors as H₂-Gas Sensors[J]. Sens Actuators B, 2007,123(1):233-239.
19. [19]
  Xiang J Y, Tu J P, Huang X H. A Comparison of Anodically Grown CuO Nanotube Film and Cu₂O Film as Anodes for Lithium Ion Batteries[J]. J Solid State Electrochem, 2008,12(7/8):941-945.
20. [20]
  Alizadeh T, Mirzagholipur S. A Nafion-Free Non-Enzymatic Amperometric Glucose Sensor Based on Copper Oxide Nanoparticles-Graphene Nanocomposite[J]. Sens Actuators B, 2014,198:438-447.
21. [21]
  Wang H, Xu J Z, Zhu J J. Preparation of CuO Nanoparticles by Microwave Irradiation[J]. J Cryst Growth, 2002,244(1):88-94.
22. [22]
  Suzuki K, Tanaka N, Ando A. Size-Selected Copper Oxide Nanoparticles Synthesized by Laser Ablation[J]. J Nanopart Res, 2012,14(5):1-11.
23. [23]
  Kumar R V, Diamant Y, Gedanken A. Sonochemical Synthesis and Characterization of Nanometer-Size Transition Metal Oxides from Metal Acetates[J]. Chem Mater, 2000,12(8):2301-2305.
24. [24]
  Zhu J W, Li D, Chen H Q. Highly Dispersed CuO Nanoparticles Prepared by a Novel Quick-Precipitation Method[J]. Mater Lett, 2004,58(26):3324-3327.
25. [25]
  Arvand M, Ardaki M S, Zanjanchi M A. A New Sensing Platform Based on Electrospun Copper Oxide/Ionic Liquid Nanocomposite for Selective Determination of Risperidone[J]. RSC Adv, 2015,5(51):40578-40587.
26. [26]
  LUO Yunfeng, LIU Baoshuang, LI Chunxiang. All Solid-State Calcium Ion Selective Electrode Based on Carbon Nanotube/Ag/MoS₂ Transducer[J]. Chinese J Appl Chem, 2019,36(6):704-710.
27. [27]
  XU Siyuan, LEI Ping, JIN Guanping. Determination of Pb(Ⅱ), Cd(Ⅱ) with Melamine Chelating Resin/Multi-walled Carbon Nanotubes Composites Modified Waxed Graphite Electrode[J]. Chinese J Appl Chem, 2014,31(2):206-211.
28. [28]
  YU Hao, ZHENG Xiaochen, LIU Rantong. Preparation of Copper-iron Hexacyanoferrate Loaded Multi-walled Carbon Nanotubes Modified Electrode for the Determination of Nitrite[J]. Chinese J Appl Chem, 2014,31(11):1336-1344.
29. [29]
  MENG Kuikui, CUO Jialing, YUN Yangfang. Simultaneous Sensitive Determination of Catechol and Hydroquinone at Gold Nanoparticles Modified Glassy Carbon Electrode[J]. Chem Res Appl, 2018,30(3):432-436.
30. [30]
  Zhang H Q, Huang Y H, Hu S R. Self-assembly of Graphitic Carbon Nitride Nanosheets-Carbon Nanotube Composite for Electrochemical Simultaneous Determination of Catechol and Hydroquinone[J]. Electrochim Acta, 2015,176:28-35.
31. [31]
  Hu F X, Chen S H, Wang C Y. Study on the Application of Reduced Graphene Oxide and Multiwall Carbon Nanotubes Hybrid Materials for Simultaneous Determination of Catechol, Hydroquinone, p-Cresol and Nitrite[J]. Anal Chim Acta, 2012,724:40-46.
32. [32]
  Goulart L A, Goncalves R, Correa A A. Synergic Effect of Silver Nanoparticles and Carbon Nanotubes on the Simultaneous Voltammetric Determination of Hydroquinone, Catechol, Bisphenol A and Phenol[J]. Microchim Acta, 2017,185(1):1-9.
33. [33]
  WAN Qijin, LIAO Hualing, LIU Yi. Simultaneous Determination of Catechol and Hydroquinpne in Graphene Modified Electrode[J]. J Wuhan Inst Tech, 2013,35(2):16-23.
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