Citation: QIAO Zongwen, ZHAO Benbo. Properties of Sulfonated Polysulfone Proton Exchange Membranes Based on One-Pot Method[J]. Chinese Journal of Applied Chemistry, ;2020, 37(6): 658-665. doi: 10.11944/j.issn.1000-0518.2020.06.190355 shu

Properties of Sulfonated Polysulfone Proton Exchange Membranes Based on One-Pot Method

QIAO Zongwen ^1,, ,
ZHAO Benbo ²

a.
Department of Chemical Engineering, Shaanxi Institute of Technology, Xi'an 710300, China
b.
Department of Chemical Engineering, North University of China, Taiyuan 030051, China

Corresponding author: QIAO Zongwen, qiaozongwen@126.com
Received Date: 27 December 2019
Revised Date: 10 March 2020
Accepted Date: 7 April 2020

Fund Project: the Youth Talent Promotion Plan of Xi′an Association for Science and Technology and Science Research Program of Shaanxi Institute of Technology Gfy18-04the Natural Science Special Project of Shaanxi Province 2019JQ-927Supported by the Natural Science Special Project of Shaanxi Province(No.2019JQ-927), and the Youth Talent Promotion Plan of Xi′an Association for Science and Technology and Science Research Program of Shaanxi Institute of Technology(No.Gfy18-04)

Figures(6)

Ethyl isocyanate polysulfone (PS-SA) was prepared by introducing the —NCO active group onto the main chain of bisphenol A polysulfones matrix by the Friedel-Crafts alkylation reaction. Naphthalene sulfonic acid modified polysulfone (PS-NS) was obtained by using 2-naphthol-6, 8-disulfonic acid dipotassium as the nucleophilic reagent in one pot. The PS-NS proton exchange membranes(PEMs) were fabricated by solution casting. The relationship between temperature and the basic properties including water uptake, swelling ratio and proton conductivity were explored. PS-NS exhibits excellent dimensional stability at high water sorption because they can form phase separation structure by locating the hydrophilic group far away from the main chain of polysulfones. The water uptake of PS-NS-4 PEMs(the bonding amount of sulfonic groups is 1.42 mmol/g) is as high as 27.2% at 25 ℃ and 40.3% at 85 ℃, but the corresponding swelling ratio is only 25.2% and 57.2%. The properties are very close to that of Nafion115 membrane under the same condition.
- polysulfone,
- ethyl isocyanate,
- naphthalene sulfonic acid type,
- micro-phase separation,
- dimensional stability
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