Citation: ZHANG Xiaobo, XIN Haiying, XU Shuang, ZHANG Xinghai, WANG Liqiu. Cellulose Gel Polymer Electrolytes and Its Application in Supercapacitors[J]. Chinese Journal of Applied Chemistry, ;2020, 37(5): 547-554. doi: 10.11944/j.issn.1000-0518.2020.05.190327 shu

Cellulose Gel Polymer Electrolytes and Its Application in Supercapacitors

ZHANG Xiaobo ^a ,
XIN Haiying ^a ,
XU Shuang ^a ,
ZHANG Xinghai ^b,, ,
WANG Liqiu ^a,c,,

a.
College of Environmental and Chemical Engineering, Yanshan University, Qinhuangdao, Hebei 066004, China
b.
School of Physical Education, Yanshan University, Qinhuangdao, Hebei 066004, China
c.
Key Laboratory of Advanced Energy Materials Chemistry(Ministry of Education), College of Chemistry, Nankai University, Tianjin 300071, China

Corresponding author: ZHANG Xinghai, xinghaizhang@tom.com WANG Liqiu, liqiuwang@tom.com
Received Date: 1 December 2019
Revised Date: 16 January 2020
Accepted Date: 19 February 2020

Fund Project: Supported by Hebei Natural Science Foundation(No.B2019203500), the Open Fund of Key Laboratory of Advanced Energy Materials Chemistry, Ministry of Education(2018) and Hebei Social Science Foundation(No.HB18TY020)the Open Fund of Key Laboratory of Advanced Energy Materials Chemistry, Ministry of Education 2018Hebei Social Science Foundation HB18TY020Hebei Natural Science Foundation B2019203500

Figures(7)

A cellulose gel electrolyte (XWD-NaOH) was obtained through static hydration and crosslinking of cellulose pulp viscose solution, followed by introducing potassium ferrocyanide into XWD-NaOH to give a gel electrolyte (XWD-NaOH-K₄[Fe(CN)₆]). XWD-NaOH-K₄[Fe(CN)₆] has excellent redox activity and ionic conductivity (15.3 mS/cm). At 0.5 A/g current density, XWD-NaOH-K₄[Fe(CN)₆] electrolyte supercapacitor exhibits an increase of the electrode specific capacitance, power density and energy density by 57%, 111% and 214% compared to those of XWD-NaOH system. The XWD-NaOH-K₄[Fe(CN)₆] system has low internal resistance, charge transfer resistance and high cycle stability
- cellulose pulp,
- gel polymer electrolyte,
- potassium ferrocyanide,
- supercapacitor
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