Citation: CAI Zhifeng, CHEN Siying, PANG Shulin, SONG Shuang, JIA Kang, MAO Yujin, TIAN Fang, ZHANG Caifeng. Synthesis of 2-Mercaptobenzimidazole-Functionalized Water-Soluble Copper Nanoclusters and Their Application to the Determination of Ag⁺[J]. Chinese Journal of Applied Chemistry, ;2020, 37(5): 587-594. doi: 10.11944/j.issn.1000-0518.2020.05.190312 shu

Synthesis of 2-Mercaptobenzimidazole-Functionalized Water-Soluble Copper Nanoclusters and Their Application to the Determination of Ag⁺

CAI Zhifeng ^a ,
CHEN Siying ^a ,
PANG Shulin ^a ,
SONG Shuang ^a ,
JIA Kang ^a ,
MAO Yujin ^a ,
TIAN Fang ^a,, ,
ZHANG Caifeng ^a,b,,

a.
Department of Chemistry
b.
Humic Acid Engineering and Technology Research Center of Shanxi Province, Taiyuan Normal University, Jinzhong, Shanxi 030619, China

Corresponding author: TIAN Fang, tianfqq@sina.com ZHANG Caifeng, zhangcf301@yahoo.com.cn
Received Date: 20 November 2019
Revised Date: 4 January 2020
Accepted Date: 20 February 2020

Fund Project: Supported by the Shanxi Provincial Applied Fundamental Research Fund Project(No.201801D121257)the Shanxi Provincial Applied Fundamental Research Fund Project 201801D121257

Figures(7)

We reported a direct one-pot approach, employing 2-mercaptobenzimidazole as a protective agent, polyvinyl pyrrolidone as a stabilizer and hydrazine hydrate as a reducing agent, for rapid preparation of highly stable, strong fluorescent, large Stokes shift fluorescent copper nanoclusters (Cu NCs) from Cu(NO₃)₂ in aqueous solution at room temperature. Meanwhile, we studied the possibility of the Cu NCs to detect silver ion in water samples. The structure of Cu NCs was characterized by transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS). The optical performance was studied using fluorescence spectroscopy and UV-visible absorption spectroscopy. The as-prepared Cu NCs exhibit a fluorescence emission at 559 nm, and show colorless and orange fluorescence under sunlight and UV light irradiation, respectively. The Cu NCs were highly dispersed with the size of 2~3 nm. In addition, it exhibits good water solubility, excellent photostability and high stability toward high concentration of sodium chloride. Under optimal reaction conditions, the Cu NCs can be used for the highly sensitive and selective detection of silver ions (Ag⁺) in aqueous solution. The fluorescence intensity quenches linearly within the range of 1 to 40 μmol/L with high sensitivity (LOD=0.5 μmol/L, S/N=3) and this sensing system has been successfully applied for environmental water sample analysis.
- copper nanoclusters,
- 2-mercaptobenzimidazole,
- silver ions,
- quenching
1. [1]
  Vasileiadis S, Brunetti G, Marzouk E. Silver Toxicity Thresholds for Multiple Soil Microbial Biomarkers[J]. Environ Sci Technol, 2018,52(15):8745-8755. doi: 10.1021/acs.est.8b00677
2. [2]
  Zhang J F, Zhou Y, Yoon J. Recent Progress in Fluorescent and Colorimetric Chemosensors for Detection of Precious Metal Ions(Silver, Gold and Platinum Ions)[J]. Chem Soc Rev, 2011,40(7):3416-3429. doi: 10.1039/c1cs15028f
3. [3]
  Leslee D B C, Karuppannan S, Karmegam M V. A Fluorescent Turn-On Carbazole-Rhodanine Based Sensor for Detection of Ag⁺ Ions and Application in Ag⁺ Ions Imaging in Cancer Cells[J]. J Fluoresc, 2019,29(1):75-89. doi: 10.1007/s10895-018-2312-6
4. [4]
  Xie Y F, Cheng Y Y, Liu M L. A Single Gold Nanoprobe for Colorimetric Detection of Silver(I) Ions with Dark-Field Microscopy[J]. Analyst, 2019,144(6):2011-2016. doi: 10.1039/C8AN02397B
5. [5]
  Baron M G, Herrin R T, Armstrong D E. The Measurement of Silver in Road Salt by Electrothermal Atomic Absorption Spectrometry[J]. Analyst, 2000,125(1):123-126.
6. [6]
  Manzoori J L, Abdolmohammad-Zadeh H, Amjadi M. Ultra-trace Determination of Silver in Water Samples by Electrothermal Atomic Absorption Spectrometry after Preconcentration with a Ligand-less Cloud Point Extraction Methodology[J]. J Hazard Mater, 2007,144(1/2):458-463.
7. [7]
  Mohadesi A, AliTaher M. Stripping Voltammetric Determination of Silver(I) at Carbon Paste Electrode Modified with 3-Amino-2-mercapto Quinazolin-4(3H)-one[J]. Talanta, 2007,71(2):615-619. doi: 10.1016/j.talanta.2006.05.001
8. [8]
  Singh R P, Pambid E R. Selective Separation of Silver from Waste Solutions on Chromium(III) Hexacyanoferrate(III) Ion Exchanger[J]. Analyst, 1990,115(3):301-304.
9. [9]
  Katarina R K, Takayanagi T, Oshima M. Synthesis of a Chitosan-Based Chelating Resin and Its Application to the Selective Concentration and Ultratrace Determination of Silver in Environmental Water Samples[J]. Anal Chim Acta, 2006,558(1/2):246-253.
10. [10]
  Ceresa A, Radu A, Peper S. Rational Design of Potentiometric Trace Level Ion Sensors. A Ag⁺-Selective Electrode with a 100 ppt Detection Limit[J]. Anal Chem, 2002,74(16):4027-4036. doi: 10.1021/ac025548y
11. [11]
  Kamel G M, El-Nahass M N, El-Khouly M E. Simple, Selective Detection and Efficient Removal of Toxic Lead and Silver Metal Ions Using Acid Red 94[J]. RSC Adv, 2019,9(15):8355-8363. doi: 10.1039/C9RA00464E
12. [12]
  Liu Z X, Liu Y M, Lu S H. A Highly Selective TPE-based AIE Fluorescent Probe is Developed for the Detection of Ag⁺[J]. RSC Adv, 2018,8(35):19701-19706. doi: 10.1039/C8RA03591A
13. [13]
  Jiang Y B, Gao C, Zhang X. A Highly Selective and Sensitive Fluorescence Probe with A-π-D-π-A Structure for Detection of Ag⁺[J]. J Mol Struct, 2018,1163:33-40. doi: 10.1016/j.molstruc.2018.01.058
14. [14]
  Wei G, Jiang Y L, Wang F. A Novel AIEE Polymer Sensor for Detection of Hg²⁺ and Ag⁺ in Aqueous Solution[J]. J Photochem Photobiol A, 2018,358:38-43. doi: 10.1016/j.jphotochem.2018.03.006
15. [15]
  Li M Q, Liao H W, Deng Q L. Preparation of an Intelligent Hydrogel Sensor Based on g-C₃N₄ Nanosheets for Selective Detection of Ag⁺[J]. J Macromol Sci A, 2018,55(5):408-413. doi: 10.1080/10601325.2018.1453260
16. [16]
  Jiang X D, Xu W C, Chen X. Colorimetric Assay for Ultrasensitive Detection of Ag(I) Ions Based on the Formation of Gold Nanoparticle Oligomers[J]. Anal Bioanal Chem, 2019,411(11):2439-2445. doi: 10.1007/s00216-019-01685-6
17. [17]
  Guo Y M, Cao F P, Lei X L. Fluorescent Copper Nanoparticles:Recent Advances in Synthesis and Applications for Sensing Metal Ions[J]. Nanoscale, 2016,8(9):4852-4863. doi: 10.1039/C6NR00145A
18. [18]
  Yang K C, Wang Y Y, Lu C S. Ovalbumin-directed Synthesis of Fluorescent Copper Nanoclusters for Sensing both Vitamin B₁ and Doxycycline[J]. J Fluoresc, 2018,196:181-186.
19. [19]
  Tang T, Ouyang J, Hu L S. Synthesis of Peptide Templated Copper Nanoclusters for Fluorometric Determination of Fe(III) in Human Serum[J]. Microchim Acta, 2016,183(10):2831-2836. doi: 10.1007/s00604-016-1935-z
20. [20]
  Wang C X, Cheng H, Huang Y J. Facile Sonochemical Synthesis of pH-Responsive Copper Nanoclusters for Selective and Sensitive Detection of Pb²⁺ in Living Cells[J]. Analyst, 2015,140(16):5634-5639. doi: 10.1039/C5AN00741K
21. [21]
  Aparna R S, Syamchand S S, George S. Tannic Acid Stabilised Copper Nanocluster Developed Through Microwave Mediated Synthesis as a Fluorescent Probe for the Turn on Detection of Dopamine[J]. J Clust Sci, 2017,28(4):2223-2238. doi: 10.1007/s10876-017-1221-1
22. [22]
  Gui R J, Sun J, Cao X L. Multidentate Polymers Stabilized Water-Dispersed Copper Nanoclusters:Facile Photoreduction Synthesis and Selective Fluorescence Turn-on Response[J]. RSC Adv, 2014,4(55):29083-29088. doi: 10.1039/C4RA03606A
23. [23]
  Bagheri H S, Afkhami A, Khoshsafar H. Protein Capped Cu Nanoclusters-SWCNT Nanocomposite as a Novel Candidate of High Performance Platform for Organophosphates Enzymeless Biosensor[J]. Biosens Bioelectron, 2017,89(2):829-836.
24. [24]
  Zhang Y Y, Li Y X, Zhang C Y. Fluorescence Turn-on Detection of Alkaline Phosphatase Activity Based on Controlled Release of PEI-Capped Cu Nanoclusters from MnO₂ Nanosheets[J]. Anal Bioanal Chem, 2017,409(20):4771-4778. doi: 10.1007/s00216-017-0420-9
25. [25]
  Ai L, Jiang W R, Liu Z Y. Engineering a Red Emission of Copper Nanocluster Self-assembly Architectures by Employing Aromatic Thiols as Capping Ligands[J]. Nanoscale, 2017,9(34):12618-12627. doi: 10.1039/C7NR03985A
26. [26]
  Sun J, Yue Y, Wang P. Facile and Rapid Synthesis of Water-Soluble Fluorescent Gold Nanoclusters for Sensitive and Selective Detection of Ag⁺[J]. J Mater Chem C, 2016,1:908-913.
27. [27]
  Luo T T, Zhang S T, Wang Y J. Glutathione-Stabilized Cu Nanocluster-Based Fluorescent Probe for Sensitive and Selective Detection of Hg²⁺ in Water[J]. Luminescence, 2017,32:1092-1099. doi: 10.1002/bio.3296
28. [28]
  Jayasree M, Aparna S S, Anjana R R. Fluorescence Turn on Detection of Bilirubin Using Fe(III) Modulated BSA Stabilized Copper Nanocluster; A Mechanistic Perception[J]. Anal Chim Acta, 2018,1031:152-160. doi: 10.1016/j.aca.2018.05.026
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis of 2-Mercaptobenzimidazole-Functionalized Water-Soluble Copper Nanoclusters and Their Application to the Determination of Ag+

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通讯作者: 陈斌, bchen63@163.com

Synthesis of 2-Mercaptobenzimidazole-Functionalized Water-Soluble Copper Nanoclusters and Their Application to the Determination of Ag⁺