Citation: WANG Wei, LI Juan, BAI Ru, HAN Zhen, FENG Xuewei, SUN Yue. Preparation of Au/Polyacrylamide@Graphene Oxide/ Nano-palladium Electrode via Metal-Free Visible-Light-Induced Atom Transfer Radical Polymerization and Its Detection of Ethanol[J]. Chinese Journal of Applied Chemistry, ;2020, 37(5): 595-603. doi: 10.11944/j.issn.1000-0518.2020.05.190299 shu

Preparation of Au/Polyacrylamide@Graphene Oxide/ Nano-palladium Electrode via Metal-Free Visible-Light-Induced Atom Transfer Radical Polymerization and Its Detection of Ethanol

College of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian, Liaoning 116029, China

Corresponding author: SUN Yue, yuesun@lnnu.edu.cn
Received Date: 8 November 2019
Revised Date: 3 January 2020
Accepted Date: 19 February 2020

Fund Project: the National Natural Science Foundation of China 21304041SSupported by the National Natural Science Foundation of China(No.21304041), the Dalian High-Level Talent Innovation Support Project(No.2016RQ047), the Science Research Project of Education Department of Liaoning Province(No.LQ2019022), and the Liaoning Normal University Innovation Training Program(No.201910165215)the Dalian High-Level Talent Innovation Support Project 2016RQ047the Science Research Project of Education Department of Liaoning Province LQ2019022the Liaoning Normal University Innovation Training Program 201910165215

Figures(6)

Polyacrylamide@graphene oxide/nano-palladium composite was prepared on the surface of gold electrode (Au/PAM@GO/Pd) by metal-free visible light-induced atom transfer radical polymerization (MVL ATRP). The Au/PAM@GO/Pd electrode was characterized by cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDS). The results show that the composite is successfully prepared on the surface of the gold electrode. The Au/PAM@GO/Pd electrode could be used as an electrochemical sensor to detect ethanol by differential pulse voltammetry (DPV). Under the optimal conditions, the linear range is 1.0×10^-8~1.0 mol/L, and the detection limit (S/N=3) is 1.3×10^-9 mol/ L, with a coefficient of 0.996.
- atom transfer radical polymerization,
- graphene oxide,
- nano-palladium,
- sensor
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