Citation: FAN Liangjiao, TIAN Yuqin, QIAN Qin, CHEN Lei, GUO Hongwei, XIN Aiyuan, HOU Wanguo. Rheological Properties of Xanthan Gum/Guar Gum Mixed Solution and Its Borax-Crosslinked System[J]. Chinese Journal of Applied Chemistry, ;2020, 37(5): 531-540. doi: 10.11944/j.issn.1000-0518.2020.05.190293 shu

Rheological Properties of Xanthan Gum/Guar Gum Mixed Solution and Its Borax-Crosslinked System

FAN Liangjiao ^a ,
TIAN Yuqin ^b ,
QIAN Qin ^b ,
CHEN Lei ^b ,
GUO Hongwei ^b ,
XIN Aiyuan ^b ,
HOU Wanguo ^a,,

a.
Key Laboratory for Colloid and Interface Chemistry(Ministry of Education), Shandong University, Ji'nan 250100, China
b.
Petroleum Engineering Technology Research Institute, Shengli Oilfield Branch, Sinopec, Dongying, Shandong 257000, China

Corresponding author: HOU Wanguo, wghou@sdu.edu.cn
Received Date: 31 October 2019
Revised Date: 13 January 2020
Accepted Date: 2 March 2020

Fund Project: Supported by the National Key R&D Program During the 13th Five-Year Plan Period of China(No.2016ZX05040-005), the Key Scientific and Technological Research Projects of Sinopec(No.P18048-2)the National Key R&D Program During the 13th Five-Year Plan Period of China 2016ZX05040-005the Key Scientific and Technological Research Projects of Sinopec P18048-2

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The rheological properties of xanthan (XG) /guar gum (GG) mixed solutions and their borax-crosslinked systems were investigated at a total solution concentration of 2.00 g/L. The synergistic interaction viscosification efficiency between XG and GG as well as the influence of solution composition, pH, and electrolytes (NaCl and CaCl₂) on the rheological properties were discussed. Under the studied conditions, all solution systems including pure XG, pure GG, and mixed XG/GG solutions as well as their borax-crosslinked systems behave as pseudoplastic fluids, and the rheological curves can be described by the Herschel-Bulkley and Casson models. The mixing of XG and GG exhibits a significant "synergistic viscosification effect". When the mass fraction of XG in the two polymers (w(XG)) is 20% and 90%, maximum values of the synergistic viscosification rate (R_m) are observed, which are 42% and 34%, respectively. The XG/GG mixed solutions can be crosslinked by borax, and the crosslinking effect is enhanced with a decrease in w(XG) or an increase in borax mass concentration (ρ(B)). At w(XG)=50% and ρ(B)=1.00 g/L, the crosslinking viscosification rate (R) is up to 85%. In the studied pH range (6.2~10.0), there is no obvious change in the rheological properties for XG/GG mixed solutions, while for the borax-crosslinked systems (w(XG)=50% and ρ(B)=0.75~1.00 g/L), the apparent viscosity initially increases and then decreases, showing a maximum value at pH=9.0, and the corresponding R is up to ~107%. The addition of electrolytes (NaCl and CaCl₂) leads to a significant decrease in the viscosity for the crosslinked XG/GG/B solution (w(XG)=10% and ρ(B)=0.50 g/L), and the influence of CaCl₂ is more obvious than that of NaCl. These results may deepen the understanding of rheological behavior of XG/GG mixed solutions and provide important information for their practical applications such as in the enhanced oil recovery.
- xanthan gum,
- guar gum,
- borax,
- synergistic interaction,
- crosslinking,
- rheology,
- viscosity
1. [1]
  Petri D F S. Xanthan Gum:A Versatile Biopolymer for Biomedical and Technological Applications[J]. J Appl Polym Sci, 2015,132(32)42035.
2. [2]
  Khouryieh H A, Herald T J, Aramouni F. Intrinsic Viscosity and Viscoelastic Properties of Xanthan/Guar Mixtures in Dilute Solutions:Effect of Salt Concentration on the Polymer Interactions[J]. Food Res Int, 2007,40(7):883-893. doi: 10.1016/j.foodres.2007.03.001
3. [3]
  Casas J A, Mohedano A F, García-Ochoa F. Viscosity of Guar Gum and Xanthan/Guar Gum Mixture Solutions[J]. J Sci Food Agric, 2000,80(12):1722-1727. doi: 10.1002/1097-0010(20000915)80:12<1722::AID-JSFA708>3.0.CO;2-X
4. [4]
  Koop H S, de Freitas R A, de Souza M M. Topical Curcumin-Loaded Hydrogels Obtained Using Galactomannan from Schizolobium Parahybae and Xanthan[J]. Carbohydr Polym, 2015,116(13):229-236.
5. [5]
  Finley J W, Soto-Vaca A, Heimbach J. Safety Assessment and Caloric Value of Partially Hydrolyzed Guar Gum[J]. J Agric Food Chem, 2013,61(8):1756-1771. doi: 10.1021/jf304910k
6. [6]
  Jang H Y, Zhang K, Chon B H. Enhanced Oil Recovery Performance and Viscosity Characteristics of Polysaccharide Xanthan Gum Solution[J]. J Ind Eng Chem, 2015,21:741-745. doi: 10.1016/j.jiec.2014.04.005
7. [7]
  JI Yi, LI Zongshi, QIAO Weihong. Chemical Modification of Guar Gum[J]. China Surfactant Deterg Cosmet, 2005,35(2):111-114. doi: 10.3969/j.issn.1001-1803.2005.02.013
8. [8]
  Mokhtari M, Ozbayoglu E M. Laboratory Investigation on Gelation Behavior of Xanthan Crosslinked with Borate Intended to Combat Lost Circulation[C]. Tunisia: Society of Petroleum Engineers(SPE), 2010: 136094.
9. [9]
  Mundargi R C, Patil S A, Aminabhavi M. Evaluation of Acrylamide-Grafted-Xanthan Gum Copolymer Matrix Tablets for Oral Controlled Delivery of Antihypertensive Drugs[J]. Carbohydr Polym, 2007,69(1):130-141. doi: 10.1016/j.carbpol.2006.09.007
10. [10]
  Wang X, Xin H, Zhu W. Synthesis and Characterization of Modified Xanthan Gum Using Poly(Maleic Anhydride/1-Octadecene)[J]. Colloid Polym Sci, 2016,294(8):1333-1341. doi: 10.1007/s00396-016-3898-3
11. [11]
  Zhang Z, Pan H, Liu P. Boric Acid Incorporated on the Surface of Reactive Nanosilica Providing a Nano-crosslinker with Potential in Guar Gum Fracturing Fluid[J]. J Appl Polym Sci, 2017,134(27)45037. doi: 10.1002/app.45037
12. [12]
  Bilanovic D, tarosvetsky J, Armon R H. Cross-Linking Xanthan and Other Compounds with Glycerol[J]. Food Hydrocolloid, 2015,44:129-135. doi: 10.1016/j.foodhyd.2014.09.024
13. [13]
  LIU Ru, LI Haiping, HOU Wanguo. Synthesis of Sodium Trimetaphosphate Crosslinked Xanthan Gum and Rheological Properties of Its Aqueous Solution[J]. Chinese J Appl Chem, 2015,32(9):1061-1069.
14. [14]
  YANG Tingting, LI Haiping, HOU Wanguo. Rheological Properties and Temperature Resistance of Epichlorohydrin Crosslinked Xanthan Gum Aqueous Solutions[J]. Polym Mater Sci Eng, 2015,31(5):39-43.
15. [15]
  Tako M, Nakamura S. Synergistic Interaction Between Xanthan and Guar Gum[J]. Carbohydr Res, 1985,138(2):207-213. doi: 10.1016/0008-6215(85)85104-1
16. [16]
  Wang F, Wang Y J, Sun Z. Conformational Role of Xanthan Gum in Its Interaction with Guar Gum[J]. J Food Sci, 2002,67(9):3289-3294. doi: 10.1111/j.1365-2621.2002.tb09580.x
17. [17]
  WANG Yuanlan, HUANG Shouen, LI Zhonghai. The Influence Factor on Viscosity and Microstructure of Xanthan/Guar Gum Mixed Solutions[J]. J Chinese Inst Food Sci Technol, 2009,9(4):118-123. doi: 10.3969/j.issn.1009-7848.2009.04.019
18. [18]
  Takemasa M, Nishinari K. Solution Structure of Molecular Associations Investigated Using NMR for Polysaccharides:Xanthan/Galactomannan Mixtures[J]. J Phys Chem B, 2016,120(2):3027-3037.
19. [19]
  Rocks J K. Xanthan Gum[J]. Food Technol, 1971,25(5):22-31.
20. [20]
  Higiro J, Herald T J, Alavi S. Rheological Study of Xanthan and Locust Bean Gum Interaction in Dilute Solution[J]. Food Res Int, 2007,40(4):435-447. doi: 10.1016/j.foodres.2006.02.002
21. [21]
  Shobha M S, Tharanathan R N. Rheological Behaviour of Pullulanase-Treated Guar Galactomannan on Co-Gelation with Xanthan[J]. Food Hydrocolloid, 2009,23(3):749-754. doi: 10.1016/j.foodhyd.2008.04.006
22. [22]
  Sandolo C, Bulone D, Mangione M R. Synergistic Interaction of Locust Bean Gum and Xanthan Investigated by Rheology and Light Scattering[J]. Carbohydr Polym, 2010,82(3):733-741. doi: 10.1016/j.carbpol.2010.05.044
23. [23]
  Thombare N, Jha U, Mishra S. Borax Cross-Linked Guar Gum Hydrogels as Potential Adsorbents Forwater Purification[J]. Carbohydr Polym, 2017,168:274-281. doi: 10.1016/j.carbpol.2017.03.086
24. [24]
  Walawender W P, Chen T Y, Cala D F. An Approximate Casson Fluid Model for Tube Flow of Blood[J]. Biorheology, 1975,12(2):111-119. doi: 10.3233/BIR-1975-12202
25. [25]
  Smith I H, Symes K C, Lawson C J. Influence of the Pyruvate Content of Xanthan on Macromolecular Association in Solution[J]. Int J Biol Macromol, 1981,3(2):129-134. doi: 10.1016/0141-8130(81)90078-7
26. [26]
  CHEN Jialang, LIU Chongjian. Structural Flow of Casson Fluids and Determination of Casson Rheological Parameters[J]. Acta Pet Sin, 1982(2):69-80.
27. [27]
  Kim S, Cho Y I, Hogenauer W N. A Method of Isolating Surface Tension and Yield Stress Effects in a U-Shaped Scanning Capillary-Tube Viscometer Using a Casson Model[J]. J Non-Newton Fluid, 2002,103(2/3):205-219.
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