Citation: SHE Xiaohong, DU Juan, WANG Lupei, ZHU Wenli, YANG Qiaoling, ZOU Chihui. Preparation and Properties of Tough Polyvinyl/Polyaniline/Polypyrrole/TiO₂ Conductive Hybrid Hydrogel[J]. Chinese Journal of Applied Chemistry, ;2020, 37(5): 541-546. doi: 10.11944/j.issn.1000-0518.2020.05.190267 shu

Preparation and Properties of Tough Polyvinyl/Polyaniline/Polypyrrole/TiO₂ Conductive Hybrid Hydrogel

School of Materials Science and Engineering, Sichuan University of Science and Engineering, Zigong, Sichuan 643000, China

Corresponding author: SHE Xiaohong, 724017857@qq.com
Received Date: 12 October 2019
Revised Date: 11 November 2019
Accepted Date: 18 December 2019

Fund Project: the Foundation of Introduced Talent of Sichuan University of Science and Engineering 2017RCL31Supported by the Foundation of Introduced Talent of Sichuan University of Science and Engineering(No.2017RCL31)

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In this paper, polyvinyl alcohol/polyaniline/polypyrrole/TiO₂(PVA/PANI/PPy/TiO₂) hybrid hydrogels were synthesized by the combination of sol-gel technique, in-situ oxidation polymerization and freezing-thawing method with polyvinyl alcohol (PVA), aniline (ANI) and pyrrole (Py) and butyl titanate (TBOT) as raw materials. It is found that the hybrid hydrogel has excellent mechanical properties and electrical conductivity. When n(ANI):n(Py) is 8:2 and the volume of TBOT is 100 μL, the maximum compressive stress of the hybrid hydrogel is 2.45 MPa. Meanwhile, the hybrid hydrogel has good conductivity. Under the action of external electrical source, the bulb could be lighted. When n(ANI):n(Py) is 2:8 and the volume of TBOT is 150 μL, the hybrid hydrogel has the highest conductivity of 0.25 S/m. The hybrid hydrogel is expected to have wide applications in the fields of flexible wearable electronic devices, safe ion batteries, sensors and biological devices.
- TiO₂,
- polyaniline,
- polypyrrole,
- tough conductive hybrid hydrogel
1. [1]
  Yuk H, Lu B Y, Zhao X H. Hydrogel Bioelectronics[J]. Chem Soc Rev, 2019,48(6):1642-1667. doi: 10.1039/C8CS00595H
2. [2]
  Mawad D, Lauto A, Wallace G G. Conductive Polymer Hydrogels[M]. Kalia S. Polymeric Hydrogels as Smart Biomaterials. Berlin: Springer, 2016: 19-44.
3. [3]
  Zhao Y, Liu B R, Pan L J. 3D Nanostructured Conductive Polymer Hydrogels for High-Performance Electrochemical Devices[J]. Energy Environ Sci, 2013,6(10):2856-2870. doi: 10.1039/c3ee40997j
4. [4]
  Shi Y, Yu G H. Designing Hierarchically Nanostructured Conductive Polymer Gels for Electrochemical Energy Storage and Conversion[J]. Chem Mater, 2016,28(8):2466-2477. doi: 10.1021/acs.chemmater.5b04879
5. [5]
  Zhao F, Shi Y, Pan L J. Multifunctional Nanostructured Conductive Polymer Gels:Synthesis, Properties, and Applications[J]. Acc Chem Res, 2017,50:1734-1743. doi: 10.1021/acs.accounts.7b00191
6. [6]
  Shi Y, Peng L L, Yu G H. Nanostructured Conducting Polymer Hydrogels for Energy Storage Applications[J]. Nanoscale, 2015,7(30):12796-12806. doi: 10.1039/C5NR03403E
7. [7]
  Zhang W, Feng P, Chen J. Electrically Conductive Hydrogels for Flexible Energy Storage Systems[J]. Prog Polym Sci, 2019,88:220-240. doi: 10.1016/j.progpolymsci.2018.09.001
8. [8]
  Karatepe Ö, Yıldız Y, Pamuk H. Enhanced Electrocatalytic Activity and Durability of Highly Monodisperse Pt@PPy-PANI Nanocomposites as a Novel Catalyst for the Electro-oxidation of Methanol[J]. RSC Adv, 2016,6:50851-50857. doi: 10.1039/C6RA06210E
9. [9]
  HUANG Mei. Study of PVA hydrogels system prepared by freezing-thawing method[D]. Jiangsu: Suzhou University, 2012(in Chinese).
10. [10]
  Tang X Z, Alavi S. Recent Advances in Starch, Polyvinyl Alcohol Based Polymer Blends, Nanocomposites and Their Biodegradability[J]. Carbohydr Polym, 2011,85(1):7-16. doi: 10.1016/j.carbpol.2011.01.030
11. [11]
  Liu M, Qing Y, Wu Y Q. Facile Fabrication of Superhydrophobic Surfaces on Wood Substrates via a One-Step Hydrothermal Process[J]. Appl Surf Sci, 2015,330:332-338. doi: 10.1016/j.apsusc.2015.01.024
12. [12]
  XUE Shouqing. Anti-corrosion Performance of Polypyrrole/Polyaniline Composite Conductive Polymers[J]. Chinese J Appl Chem, 2013,30(2):203-207.
13. [13]
  Ricciardi R, Auriemma F, Gaillet C. Investigation of the Crystallinity of Freeze/Thaw Poly(vinyl alcohol) Hydrogels by Different Techniques[J]. Macromolecules, 2004,37(25):9510-9516. doi: 10.1021/ma048418v
1. [1]
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2. [2]
  Hongye Bai , Lihao Yu , Jinfu Xu , Xuliang Pang , Yajie Bai , Jianguo Cui , Weiqiang Fan . Controllable Decoration of Ni-MOF on TiO2: Understanding the Role of Coordination State on Photoelectrochemical Performance. Chinese Journal of Structural Chemistry, 2023, 42(10): 100096-100096. doi: 10.1016/j.cjsc.2023.100096
3. [3]
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4. [4]
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5. [5]
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6. [6]
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7. [7]
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8. [8]
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9. [9]
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10. [10]
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11. [11]
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12. [12]
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13. [13]
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14. [14]
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15. [15]
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16. [16]
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17. [17]
  Yifen He , Chao Qu , Na Ren , Dawei Liang . Enhanced degradation of refractory organics in ORR-EO system with a blue TiO₂ nanotube array modified Ti-based Ni-Sb co-doped SnO₂ anode. Chinese Chemical Letters, 2024, 35(8): 109262-. doi: 10.1016/j.cclet.2023.109262
18. [18]
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19. [19]
  Xing Xiao , Yunling Jia , Wanyu Hong , Yuqing He , Yanjun Wang , Lizhi Zhao , Huiqin An , Zhen Yin . Sulfur-defective ZnIn2S4 nanosheets decorated by TiO2 nanosheets with exposed {001} facets to accelerate charge transfer for efficient photocatalytic hydrogen evolution. Chinese Journal of Structural Chemistry, 2024, 43(12): 100474-100474. doi: 10.1016/j.cjsc.2024.100474
20. [20]
  Shuangxi Li , Huijun Yu , Tianwei Lan , Liyi Shi , Danhong Cheng , Lupeng Han , Dengsong Zhang . NO_x reduction against alkali poisoning over Ce(SO₄)₂-V₂O₅/TiO₂ catalysts by constructing the Ce⁴⁺–SO₄²⁻ pair sites. Chinese Chemical Letters, 2024, 35(5): 108240-. doi: 10.1016/j.cclet.2023.108240

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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Properties of Tough Polyvinyl/Polyaniline/Polypyrrole/TiO2 Conductive Hybrid Hydrogel

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通讯作者: 陈斌, bchen63@163.com

Preparation and Properties of Tough Polyvinyl/Polyaniline/Polypyrrole/TiO₂ Conductive Hybrid Hydrogel