Citation: SUN Li'na, LI Yan, GUO Hantao, HUANG Tingting, YAO Bixia, WENG Wen. Preparation of Nitrogen and Iron Co-doped Carbon Nanoparticles and Their Applications in Detection of Hydrogen Peroxide and Glucose[J]. Chinese Journal of Applied Chemistry, ;2020, 37(3): 350-358. doi: 10.11944/j.issn.1000-0518.2020.03.190256 shu

Preparation of Nitrogen and Iron Co-doped Carbon Nanoparticles and Their Applications in Detection of Hydrogen Peroxide and Glucose

SUN Li'na ^a,, ,
LI Yan ^b ,
GUO Hantao ^b ,
HUANG Tingting ^b ,
YAO Bixia ^b ,
WENG Wen ^b,c

a.
College of Food Engineering, Zhangzhou Institute of Technology, Zhangzhou, Fujian 363000, China
b.
College of Chemistry, Chemical Engineering and Environment, Minnan Normal University, Zhangzhou, Fujian 363000, China
c.
Fujian Provincial Key Laboratory of Modern Analytical Science and Separation Technology, Zhangzhou, Fujian 363000, China

Corresponding author: SUN Li'na, 41573105@qq.com
Received Date: 29 September 2019
Revised Date: 19 November 2019
Accepted Date: 20 December 2019

Fund Project: the Education and Scientific Research Project for Young and Middle-aged Teachers of Fujian Province JAT171093the Natural Science Foundation of Fujian Province of China 2016Y0065the Major Science and Technology Projects of Zhangzhou City zz2018ZD20Supported by the Natural Science Foundation of Fujian Province of China(No.2016Y0065), the Major Science and Technology Projects of Zhangzhou City(No.zz2018ZD20), and the Education and Scientific Research Project for Young and Middle-aged Teachers of Fujian Province(No.JAT171093)

Figures(7)

Nitrogen and iron co-doped carbon nanoparticles (N/Fe-CNPs) were synthesized by one-pot solvothermal method using L-tartaric acid and citric acid monohydrate as mixed carbon sources with the addition of ferric chloride hexahydrate, and ethylenediamine as the nitrogen source and polymerization reagent. The as-prepared N/Fe-CNPs could catalyze 3, 3', 5, 5'-tetramethylbenzidine to produce the soluble blue product. Combined with glucose oxidase (GOx), a sensitive method for the detection of hydrogen peroxide and glucose was established. The concentration of hydrogen peroxide and glucose has a good linear relationship with the absorbance of the reaction system. The limit of detection was calculated to be 42.5 and 76.1 nmol/L for hydrogen peroxide and glucose, respectively.
- nitrogen and iron co-doped carbon nanoparticles,
- peroxidase mimetics,
- glucose oxidase,
- detection of hydrogen peroxide,
- detection of glucose
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