Citation: ZHANG Chenglu, SONG Fulu, ZHOU Long, HAN Zhen, BAI Ru, YANG Fan, WANG Nan, SUN Yuedong. Synthesis and Properties of Carboxylate Gemini Surfactants[J]. Chinese Journal of Applied Chemistry, ;2020, 37(3): 271-279. doi: 10.11944/j.issn.1000-0518.2020.03.190242 shu

Synthesis and Properties of Carboxylate Gemini Surfactants

College of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian, Liaoning 116029, China

Corresponding author: ZHANG Chenglu, zhangchenglu@lnnu.edu.cn
Received Date: 10 September 2019
Revised Date: 7 November 2019
Accepted Date: 5 December 2019

Fund Project: Supported by the Science and Technology Project of Liaoning Education Department(No.2009A426)the Science and Technology Project of Liaoning Education Department 2009A426

Figures(5)

To screen environmental friendly new gemini surfactants, five carboxylate-type gemini surfactants EODPN1-EODPN 5[2, 2'-(1, 2-CH₂CH₂-di-O-)-di-(4-C_nH_2n+1COPhCOONa), n=5, 7, 9, 11 and 13] were synthesized from salicylic acid. The structures of the target products were confirmed by nuclear magnetic resonance (NMR) spectroscopy and Fourier transform infrared (FT-IR) spectrometer. The properties of EODPN as surfactants were explored, and the relevant thermodynamic parameters were obtained by theoretical calculation using the Gibbs surface adsorption equation. The results show that EODPN has excellent surface activities, extremely low critical micelle concentration (CMC) values (minimum 0.4 mmol/L), good surface tension reduction performance (minimum 29.74 mN/m) and high surface adsorption per unit area Γ(up to 3.37×10^-6 mol/m²). By changing the length of the hydrophobic alkyl carbon chain, the surface activity and self-assembly ability of EODPN were optimized, and EODPN4 was selected as the best surfactant. Based on EODPN4 which can be stably combined with copper ions, the detection of surfactant content is realized.
- gemini surfactant,
- carboxylate,
- thermodynamic parameters,
- surface activity
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