Citation: GAO Jia, SONG Fujiao, CHENG Wenqiang, GE Yan, XU Qi. Catalytic Performance of Pd-Cu/ZrO₂ Catalyst for Hydrogenation of Carbon Dioxide to Methanol[J]. Chinese Journal of Applied Chemistry, ;2020, 37(2): 160-167. doi: 10.11944/j.issn.1000-0518.2020.02.190211 shu

Catalytic Performance of Pd-Cu/ZrO₂ Catalyst for Hydrogenation of Carbon Dioxide to Methanol

GAO Jia ^a ,
SONG Fujiao ^b ,
CHENG Wenqiang ^c ,
GE Yan ^c ,
XU Qi ^a,,

a.
School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, Jiangsu 212013, China
b.
School of Environmental Science Engineering, Yancheng Institute of Technology, Yancheng, Jiangsu 224051, China
c.
School of Chemistry and Chemical Engineering, Yancheng Institute of Technology, Yancheng, Jiangsu 224051, China

Corresponding author: XU Qi, ycxqsteve@163.com
Received Date: 31 July 2019
Revised Date: 30 September 2019
Accepted Date: 4 November 2019

Fund Project: the National Natural Science Foundation of China 21802119Supported by the National Natural Science Foundation of China(No.21802119)

Figures(6)

Cu/ZrO₂ catalysts with the Cu/Zr molar ratio of 1:1, 1:2, 1:4 and 1:8 were prepared by the sol-gel method. When n(Cu):n(Zr)=1:4, a high CO₂ conversion (8.0%) with methanol selectivity of 59.5% was achieved. To increase CO₂ conversion and CH₃OH selectivity, Pd-Cu/ZrO₂ catalyst with the Cu/Zr molar ratio of 1:4 and 1% mass fraction of Pd was synthesized by the impregnation method. The results showed that CO₂ conversion and CH₃OH yield over the Pd-Cu/ZrO₂ catalyst were 40.0% and 80.9% higher than that over the Cu/ZrO₂ catalyst at 250℃, 2 MPa, 12000 mL/(g·h) and V(H₂):V(CO₂)=3:1. Powder X-ray diffraction (XRD), Fourier transform infrared spectroscopy analysis (FT-IR), N₂ adsorption-desorption (BET), X-ray photoelectron spectroscopy (XPS) and temperature-programmed reduction of H₂(H₂-TPR) results indicated that addition of Pd improved the dispersion and surface area of the catalyst. The strong interaction between Pd and Cu species leads to the shift of Cu2p to low binding energies and decreases the catalyst reduction temperature, which exhibits high catalytic performance for hydrogenation of CO₂.
- sol-gel method,
- impregnation method,
- carbon dioxide hydrogenation,
- methanol
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沈阳化工大学材料科学与工程学院沈阳 110142

Catalytic Performance of Pd-Cu/ZrO2 Catalyst for Hydrogenation of Carbon Dioxide to Methanol

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通讯作者: 陈斌, bchen63@163.com

Catalytic Performance of Pd-Cu/ZrO₂ Catalyst for Hydrogenation of Carbon Dioxide to Methanol