Citation: WANG Qi, TONG Yuzhang, JIA Xiaopu, YANG Chun, WANG Qinglun, LIAO Daizheng. Syntheses, Crystal Structures and Magnetic Properties of a 2D Cobalt(Ⅱ) Metal-Organic Framework Based on N, N'-Bis-(3-Pyridyl) Terephthalamide and 1, 3, 5-Benzenetricarboxylic Acid[J]. Chinese Journal of Applied Chemistry, ;2019, 36(12): 1397-1405. doi: 10.11944/j.issn.1000-0518.2019.12.190125 shu

Syntheses, Crystal Structures and Magnetic Properties of a 2D Cobalt(Ⅱ) Metal-Organic Framework Based on N, N'-Bis-(3-Pyridyl) Terephthalamide and 1, 3, 5-Benzenetricarboxylic Acid

WANG Qi ^a ,
TONG Yuzhang ^b ,
JIA Xiaopu ^a ,
YANG Chun ^a,, ,
WANG Qinglun ^b,, ,
LIAO Daizheng ^b

a.
School of Chemical Engineering and Technology, Hebei University of Technology, Tianjin 300130, China
b.
Department of Chemistry, Nankai University, Tianjin 300071, China

Corresponding author: YANG Chun, ychun@hebut.edu.cn WANG Qinglun, wangql@nankai.edu.cn
Received Date: 28 April 2019
Revised Date: 29 May 2019
Accepted Date: 9 July 2019

Fund Project: the National Natural Science Foundation of China 21601092the Natural Science Foundation of Hebei Province B2016202280the Innovation and Entrepreneurship Training Program of Hebei Province for Undergraduate Students 201810080095Supported by the National Natural Science Foundation of China(No.21771111, No.21601092, No.21371104), the Natural Science Foundation of Hebei Province(No.B2016202280), and the Innovation and Entrepreneurship Training Program of Hebei Province for Undergraduate Students(No.201810080095)the National Natural Science Foundation of China 21371104the National Natural Science Foundation of China 21771111

Figures(7)

Based on N, N'-bis-(3-pyridyl)terephthalamide (3-bptpa) and 1, 3, 5-benzenetricarboxylic acid (1, 3, 5-H₃btc), a Co(Ⅱ) metal-organic framework[Co(3-bptpa)(1, 3, 5-Hbtc)]·2H₂O(1) with a 2D grid-like structure was hydrothermally synthesized. Complex 1 was characterized by X-ray crystallography, Fourier transform infrared (FT-IR) spectra, elemental analysis, thermal analysis and magnetic measurements. Each 1, 3, 5-Hbtc^2- provided one chelating and one bridging carboxylate groups to coordinate to Co(Ⅱ) cations. The centrosymmetric dimer[Co(3-bptpa)(1, 3, 5-Hbtc)]₂ was assembled into a 1D ladder-like chains by bridging carboxylate groups. The neighbouring chains were connected into 2D grid-like network by the coordination of 3-bptpa to Co(Ⅱ), resulting in the distorted CoN₂O₄ octahedral coordination sphere. The magnetic data of complex 1 in the temperature range 16~300 K were analyzed including the one-ion approximation for Co(Ⅱ) with spin-orbit coupling in O_h symmetry and intermolecular exchange interaction(zj') in the molecular field approximation leading to λ=-100.4 cm^-1 and zj'=-0.618 cm^-1.
- dipyridine diamide ligand,
- hydrothermal synthesis,
- cobalt(Ⅱ),
- metal-organic framework(MOF),
- magnetic properties
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