Citation: ZHOU Fengzhen, LI Wenqiu, WANG Wenjing, GUO Huiling. Influencing Factors of Lanthanum Adsorption by Ca-Montmorillonite and Its Application[J]. Chinese Journal of Applied Chemistry, ;2019, 36(12): 1413-1421. doi: 10.11944/j.issn.1000-0518.2019.12.190077 shu

Influencing Factors of Lanthanum Adsorption by Ca-Montmorillonite and Its Application

Hubei University of Technology, School of Bioengineering and Food, Wuhan 430068, China

Corresponding author: GUO Huiling, 405530371@qq.com
Received Date: 22 March 2019
Revised Date: 3 June 2019
Accepted Date: 3 July 2019

Fund Project: the National Natural Science Foundation of China 21401051Supported by the National Natural Science Foundation of China (No. 21401051) and the Natural Science Foundation of Hubei Province (No. 2014CFB595)the Natural Science Foundation of Hubei Province 2014CFB595

Figures(6)

The adsorption of lanthanum on Ca-montmorillonite was studied. The crystal structure, surface morphology, specific surface area and chemical structure of Ca-montmorillonite were characterized by XRD, SEM, BET, Fourier transform infrared spectrum (FT-IR) and X-Ray fluorescence (XRF). The effects of initial lanthanum concentration, pH and adsorption temperature on the adsorption of La onto Ca-montmorillonite were examined when the mass concentration of Ca-montmorillonite was 10 g/L. The phosphorus removal effect of Ca-MMT@La was studied. The results showed that the adsorption of La onto Ca-montmorillonite increases with initial lanthanum concentration increasing, and the maximum adsorption capacity is 49.62 mg/g. With the increase of the pH of lanthanum-containing solution, the adsorption capacity increases and the optimum adsorption is obtained at initial pH 6 with the adsorption capacity of 38.36 mg/g. With the increase of temperature, the adsorption capacity increases firstly and then decreases. The maximum adsorption capacity of lanthanum is 41.23 mg/g at 20℃. The adsorption equilibrium was best described by the Langmuir isotherm model. The result indicated that La is adsorbed onto Ca-montmorillonite through the monolayer adsorption. Ca-montmorillonite can not adsorb phosphorus. However, Ca-MMT@La has a strong adsorption capacity for phosphate with the adsorption capacity of 7.24 mg/g and the phosphorus removal rate of 72.41%. The adsorption of phosphorus onto Ca-MMT@La increases with the increase of loaded lanthanum content.
- Ca-montmorillonite,
- adsorbent,
- lanthanum,
- wastewater treatment,
- adsorption effect
1. [1]
  Das D, Varshini J S C, DAS N. Recovery of Lanthanum(Ⅲ) from Aqueous Solution Using Biosorbents of Plant and Animal Origin:Batch and Column Studies[J]. Miner Eng, 2014,69:40-56. doi: 10.1016/j.mineng.2014.06.013
2. [2]
  Awwad N S, Gad H M H, Ahmad M I. Sorption of Lanthanum and Erbium from Aqueous Solution by Activated Carbon Prepared from Rice Husk[J]. Colloids Surf B, 2010,81(2):593-599.
3. [3]
  Tadjarodi A, Jalalat V, Zare-Dorabei R. Adsorption of La(Ⅲ) in Aqueous Systems by N-(2-Hydroxyethyl) Salicylaldimine-Functionalized Mesoporous Silica[J]. Mater Res Bull, 2015,61:113-119. doi: 10.1016/j.materresbull.2014.09.036
4. [4]
  Jacinto J, Henriques B, Duarte A C. Removal and Recovery of Critical Rare Elements from Contaminated Waters by Living Gracilaria gracilis[J]. J Hazard Mater, 2018,344:531-538. doi: 10.1016/j.jhazmat.2017.10.054
5. [5]
  Wang Y Y, Lu H H, Liu Y X. Ammonium Citrate-Modified Biochar:An Adsorbent for La(Ⅲ) Ions from Aqueous Solution[J]. Colloids Surf A, 2016,509:550-563. doi: 10.1016/j.colsurfa.2016.09.060
6. [6]
  Chen J D, Luo W J, Guo A F. Preparation of a Novel Carboxylate-Rich Palygorskite as an Adsorbent for Ce³⁺ from Aqueous Solution[J]. J Colloid Interface Sci, 2018,512:657-664. doi: 10.1016/j.jcis.2017.09.107
7. [7]
  Li X J, Zhang X, Yang H. Atomic-Layered Mn Clusters Deposited on Palygorskite as Powerful Adsorbent for Recovering Valuable Rees from Wastewater with Superior Regeneration Stability[J]. J Colloid Interface Sci, 2018,509:395-405. doi: 10.1016/j.jcis.2017.09.041
8. [8]
  Ponoua J, Wang L P, Dodbiba G. Recovery of Rare Earth Elements from Aqueous Solution Obtained from Vietnamese Clay Minerals Using Dried and Carbonized Parachlorella[J]. J Environ Chem Eng, 2014,2:1070-1081. doi: 10.1016/j.jece.2014.04.002
9. [9]
  Sadovsky D, Brenner A, Astrachan B. Biosorption Potential of Cerium Ions Using Spirulina Biomass[J]. J Rare Earths, 2016,34(6):644-652. doi: 10.1016/S1002-0721(16)60074-1
10. [10]
  Zhao Z Y, Sun X Q, Dong Y M. Synergistic Effect of Doped Functionalized Ionic Liquids in Silica Hybrid Material for Rare Earth Adsorption[J]. Ind Eng Chem Res, 2016,55(7):2221-2229. doi: 10.1021/acs.iecr.5b04742
11. [11]
  Iftekhar S, Farooq M U, Sillanpaa M. Removal of Ni(Ⅱ) Using Multi-walled Carbon Nanotubes Electrodes:Relation Between Operating Parameters and Capacitive Deionization Performance[J]. Arab J Sci Eng, 2017,42:235-240. doi: 10.1007/s13369-016-2301-5
12. [12]
  Gao S, Luo T T, Zhou Q. A Novel and Efficient Method on the Recovery of Nanosized CeO₂ in Ce³⁺ Wastewater Remediation Using Modified Sawdust as Adsorbent[J]. J Colloid Interface Sci, 2018,512:629-637. doi: 10.1016/j.jcis.2017.09.032
13. [13]
  Diniz V, Volesky B. Biosorption of La, Eu and Yb Using Sargassum Biomass[J]. Water Res, 2005,39:239-247. doi: 10.1016/j.watres.2004.09.009
14. [14]
  Wu D B, Sun Y H, Wan Q G. Adsorption of Lanthanum(Ⅲ) from Aqueous Solution Using 2-Ethylhexyl Phosphonic Acid Mono-2-Ethylhexyl Ester-Grafted Magnetic Silica Nanocomposites[J]. J Hazard Mater, 2013,260:409-419. doi: 10.1016/j.jhazmat.2013.05.042
15. [15]
  Rahman M M, Khan S B, Marwani H M. SnO₂-TiO₂ Nanocomposites as New Adsorbent for Efficient Removal of La(Ⅲ) Ions from Aqueous Solutions[J]. J Taiwan Inst Chem Eng, 2014,45(4):1964-1974. doi: 10.1016/j.jtice.2014.03.018
16. [16]
  Koochaki-Mohammadpour S M A, Torab-Mostaedi M, Talebizadeh-Rafsanjani A. Adsorption Isotherm, Kinetic, Thermodynamic, and Desorption Studies of Lanthanum and Dysprosium on Oxidized Multiwalled Carbon Nanotubes[J]. J Dispersion Sci Technol, 2014,35:244-254. doi: 10.1080/01932691.2013.785361
17. [17]
  Anastopoulos I, Bhatnagar A, Lima E C. Adsorption of Rare Earth Metals:A Review of Recent Literature[J]. J Mol Liq, 2016,221:954-962. doi: 10.1016/j.molliq.2016.06.076
18. [18]
  Iannicelli-Zubiani E M, Cristiani C, Dotelli G. Use of Natural Clays as Sorbent Materials for Rare Earth Ions:Materials Characterization and Set Up of the Operative Parameters[J]. Waste Manage, 2015.
19. [19]
  Zhu R L, Chen Q Z, Zhou Q. Adsorbents Based on Montmorillonite for Contaminant Removal from Water:A Review[J]. Appl Clay Sci, 2016,123:239-258. doi: 10.1016/j.clay.2015.12.024
20. [20]
  Nagy K, Biro G, Berkesi O. Intercalation of Lecithins for Preparation of Layered Nanohybrid Materials and Adsorption of Limonene[J]. Appl Clay Sci, 2013,72:155-162. doi: 10.1016/j.clay.2012.11.008
21. [21]
  Cottet L, Almeida C A P, Naidek N. Adsorption Characteristics of Montmorillonite Clay Modified with Iron Oxide with Respect to Methylene Blue in Aqueous Media[J]. Appl Clay Sci, 2014,95:25-31. doi: 10.1016/j.clay.2014.03.023
22. [22]
  Zhou C H, Keeling J. Fundamental and Applied Research on Clay Minerals:From Climate and Environment to Nanotechnology[J]. Appl Clay Sci, 2013,74:3-9. doi: 10.1016/j.clay.2013.02.013
23. [23]
  Nones Janaina, Riella H G, Trentin A G. Effects of Bentonite on Different Cell Types:A Brief Review[J]. Appl Clay Sci, 2015,105:225-230.
24. [24]
  Chen Q. Study on The Adsorption of Lanthanum(Ⅲ) from Aqueous Solution by Bamboo Charcoal[J]. J Rare Earths, 2010,28:125-131. doi: 10.1016/S1002-0721(10)60272-4
25. [25]
  Rahman M L, Biswas T K, Sarkar S M. Adsorption of Rare Earth Metals from Water Using a Kenaf Cellulose-Based Poly(Hydroxamic Acid) Ligand[J]. J Mol Liq, 2017,243:616-623. doi: 10.1016/j.molliq.2017.08.096
26. [26]
  Ramasamy D L, Khan S, Repo E. Synthesis of Mesoporous and Microporous Amine and Non-Amine Functionalized Silica Gels for the Application of Rare Earth Elements(REE) Recovery from the Waste Water-Understanding the Role of pH, Temperature, Calcination and Mechanism in Light REE and Heavy REE[J]. Chem Eng J, 2017,322:56-65. doi: 10.1016/j.cej.2017.03.152
27. [27]
  De Castro L F, Brandao V S, Bertolino L C. Phosphate Adsorption by Montmorillonites Modified with Lanthanum/Iron and a Laboratory Test Using Water from the Jacarepagu Lagoon(RJ, Brazil)[J]. J Braz Chem Soc, 2019,30(3):641-657.
28. [28]
  WANG Min. Spectrophotometric Determination of Lanthanum in Catalysts with Arsenazo(Ⅲ)[J]. Chinese J Spectrosc Lab, 2014,21(2):390-392.
29. [29]
  WANG Lihua, YI Xiaodong. Preparation and Performance of Nanosized La₂O₃[J]. J Fujian Norm Univ(Nat Sci Ed), 2012,28(4):60-63.
30. [30]
  Thagira B H, Karthikeyan P, Meenakshi S. Lanthanum(Ⅲ) Encapsulated Chitosan-Montmorillonite Composite for the Adsorptive Removal of Phosphate Ions from Aqueous Solution[J]. Int J Biol Macromol, 2018,112:284-293. doi: 10.1016/j.ijbiomac.2018.01.138
31. [31]
  WAN Dong, WANG Guanghua, LI Wenbing. Preparation and Characterization of Supported Fe₃O₄ Nanoparticles with Different Modified Bentonite[J]. Ind Safe Environ Prot, 2014,9(40):27-29.
32. [32]
  LI Wenbing, ZHANG Yujia, ZHANG Xiu. Nano-Magnetic Modified Bentonite:Preparation and Its Degradation of Methyl Orange[J]. J Wuhan Univ Sci Technol, 2014,35(3):202-206.
33. [33]
  LI Wenbing, LI HaiJian, WAN Dong. Synthesis and Characterization of Pillared Bentonite Supported Fe₃O₄ Magnetic Nanoparticles Composite Material[J]. Environ Eng, 2014,32(11):77-81.
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