Citation: LIU Ning, LIU Shuilin, WU Suyun, TANG Xinde, WU Zhi, LI Aiyang. CTAB-P123-Assisted Synthesis of Orderly Mesoporous KF/Al-Ce-SBA-15 Solid Base and Its Catalytic Application[J]. Chinese Journal of Applied Chemistry, ;2019, 36(11): 1294-1300. doi: 10.11944/j.issn.1000-0518.2019.11.190081 shu

CTAB-P123-Assisted Synthesis of Orderly Mesoporous KF/Al-Ce-SBA-15 Solid Base and Its Catalytic Application

Department of Materials and Chemical Engineering, New Building Materials Academy, Hunan Institute of Technology, Hengyang, Hunan 421002, China

Corresponding author: LIU Ning, liuning0731@163.com LI Aiyang, 229469276@qq.com
Received Date: 1 April 2019
Revised Date: 10 June 2019
Accepted Date: 9 July 2019

Fund Project: Supported by the National Natural Science Foundation of China(No. 51802093), the Hunan Provincial Natural Science Foundation of China(No.2019JJ60026, No.2019JJ50107), the Foundation of Hunan Educational Committee(No.18B465), the Key Laboratory of Functional Organometallic Materials of Hengyang Normal University(No.GN18K01), and the Characteristic Application Discipline of Material Science and Engineering in Hunan(No.Xiang-Jiao-Tong[2018]369)the Characteristic Application Discipline of Material Science and Engineering in Hunan Xiang-Jiao-Tong[2018]369the Hunan Provincial Natural Science Foundation of China 2019JJ50107the Foundation of Hunan Educational Committee 18B465the National Natural Science Foundation of China 51802093the Key Laboratory of Functional Organometallic Materials of Hengyang Normal University GN18K01the Hunan Provincial Natural Science Foundation of China 2019JJ60026

Figures(5)

The orderly mesoporous KF/Al-Ce-SBA-15(KF/ACS) solid bases were successfully prepared with cetyltrimethylammonium bromide(CATB)-poly(ethylene oxide)/poly(propylene oxide)/poly(ethylene oxide) triblock copolymer (P123) as the dual-template and KF as the modifier in two steps. The structure and property of the obtained catalysts were characterized by X-ray diffraction (XRD), N₂ adsorption-desorption, transmission electron microscopy (TEM), scanning electron microscopy (SEM) and CO₂-temperature programmed desorption (TPD). The results illustrated that the KF/ACS catalysts possess both an ordered mesostructure and superbasicity when the introduced Al/Ce atomic ratio is 0.12 and the loading amounts(mass fraction) of KF is 10%. The catalytic activity of the prepared materials was evaluated in the ring-opening reaction of propylene oxide (PO) with methanol. It shows excellent catalytic performance exhibiting 92.0% yield of propylene glycol monomethyl ether (PM) and 96.1% selectivity to 1-methoxy-2-propanol (PPM) and the by-products of dipropylene glycol methyl ether was effectively inhibited.
- cetyltrimethylammonium bromide,
- triblock copolymer P123,
- mesoporous solid bases,
- SBA-15,
- Al-Ce mixed oxides
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