Citation: CHEN Chuan, XU Yingdi, XUE Xuming, ZHOU Pengpeng. Selective Oxidation of Alcohols to Carbonyl Compounds over Metalloporphyrins with MgAl Hydrotalcite Additive[J]. Chinese Journal of Applied Chemistry, ;2019, 36(11): 1286-1293. doi: 10.11944/j.issn.1000-0518.2019.11.190073 shu

Selective Oxidation of Alcohols to Carbonyl Compounds over Metalloporphyrins with MgAl Hydrotalcite Additive

College of Chemical & Materials Engineering, Changzhou Vocational Institute of Engineering, Changzhou, Jiangsu 213164, China

Corresponding author: CHEN Chuan, 8000000705@czie.edu.cn XUE Xuming, 8000000664@czie.edu.cn
Received Date: 19 March 2019
Revised Date: 29 April 2019
Accepted Date: 27 May 2019

Fund Project: Jiangsu Education Department, Construction of Brand Speciality in 2015 in Jiangsu Province PPZY2015B178Supported by Jiangsu Education Department, Construction of Brand Speciality in 2015 in Jiangsu Province(No.PPZY2015B178)

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The selective aerobic oxidation of alcohols to carbonyl compounds was achieved by introduction of MgAl hydrotalcite into the metallotetraphenylporphyrins(MTPPs, M=Co, Fe, Mn, Ni) catalytic oxidation system. The results indicated that CoTPP exhibited the highest catalytic activity in the oxidation of benzyl alcohol to benzaldehyde through molecular oxygen/isobutyraldehyde(IBA) system, and MgAl hydrotalcite additive could effectively improve the catalytic selectivity of aldehyde. Under the optimized conditions(benzyl alcohol 1 mmol, acetonitrile 2 mL, CoTPP 5 mg, MgAl hydrotalcite 18 mg, IBA 5 mmol, reaction temperature 60℃, oxygen atmosphere, reaction time 2 h), the conversion of benzyl alcohol and the selectivity of benzaldehyde reached 94% and 92%, respectively. The catalytic system also exhibited good catalytic performance in the oxidation of other benzylic alcohols.
- cobalt porphyrin,
- hydrotalcite,
- alcohol,
- selective oxidation,
- base
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