Citation: HU Xueyi, LUO Minmin, FANG Yun, LI Junguo, SUN Yang, LI Huashan. A Comparative Study on the Formation of Nitrosamines of Ethanolamines[J]. Chinese Journal of Applied Chemistry, ;2019, 36(9): 1061-1068. doi: 10.11944/j.issn.1000-0518.2019.09.190029 shu

A Comparative Study on the Formation of Nitrosamines of Ethanolamines

HU Xueyi ^a ,
LUO Minmin ^a ,
FANG Yun ^a,, ,
LI Junguo ^b ,
SUN Yang ^c ,
LI Huashan ^c

a.
Key Laboratory of Synthetic and Biological Colloids(Ministry of Education), School of Chemical and Material Engineering, Jiangnan University, Wuxi, Jiangsu 214122, China
b.
Jiangsu Qingting Washing Products Co., Ltd., Yancheng, Jiangsu 224555, China
c.
Nanjing Huashi New Material Co., Ltd., Nanjing 210044, China

Corresponding author: FANG Yun, yunfang@126.com
Received Date: 25 January 2019
Revised Date: 21 March 2019
Accepted Date: 10 April 2019

Fund Project: Supported by the National Key Research and Development Plan of China(No.2017YFB0308904)the National Key Research and Development Plan of China No.2017YFB0308904

Figures(5)

To investigate the reasonability and feasibility to substitute fatty acid diethanolamide by monoethanolamide and methylethanolamide in surfactant production and application, the nitrosation of methylethanolamine or monoethanolamine was compared with diethanolamine. In this study, nitrosamines were prepared from three ethanolamines by nitrosating agents of both tert-butyl nitrite and nitrous acid. The products of nitrosation by tert-butyl nitrite were identified to reveal nitrosation mechanisms, while the yields of the nitrosamines formed by nitrous acid were used to evaluate the easiness of nitrosation among three ethanolamines. Mechanism analysis of nitrosation shows that diethanolamine or methylethanolamine forms the corresponding nitrosamines, while monoethanolamine solely forms trace amount of N-nitroso-diethanolamine owing to the formation of intermediate diethanolamine by disproportionation of monoethanolamine. The experimental results also reveal that methylethanolamine and monoethanolamine are more difficult to form nitrosamines than diethanolamine. Therefore, it is reasonable and feasible to substitute fatty acid diethanolamide by monoethanolamide and methylethanolamide in surfactant production and application, which has theoretical and practical significance for safeguarding human health and safety.
- fatty acid alkanolamides,
- surfactant,
- nitrosamine,
- ethanolamine compound,
- nitrosation mechanism
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